Crystal structure of bis­{(Z)-(benzyl­amino)[(5Z)-2-(benzyl­imino-κN)-5-(2-meth­oxy-2-oxo­ethyl­idene)-4-oxo­thio­lan-3-yl­idene]methane­thiol­ato-κS}copper(II)

Acta Crystallographica Section E: Crystallographic Communications

Slepukhin, P.¹  Obydennov, K.²  Khamidullina, L.²  Morzherin, Y.² 

[1] I. Postovsky Institute of Organic Synthesis, Kovalevskoy 22 Ekaterinburg 620090, Russian Federation;Ural Federal University, Mira 19 Ekaterinburg 620002, Russian Federation

关键词: CRYSTAL STRUCTURE;    COPPER(II) COMPLEX;    THIOAMIDE;   

DOI  :  10.1107/S2056989015005022

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title complex, [Cu(C22H19N2O3S2)2], was obtained from the reaction between (Z)-methyl 2-(5-benzyl­imino-4-benzyl­carbamo­thioyl-3-oxo­thio­lan-2-yl­idene)acetate and Cu(NO3)2. The CuII atom is tetra­coordinated by two N,S-bidentate ligands, forming a highly distorted tetra­hedral environment. The structure displays two intra­molecular N—H⋯O hydrogen bonds.

【 授权许可】

CC BY