Crystal structure of {N-[(6-bromo­pyridin-2-yl)(phen­yl)methyl­idene]-2,6-di­methyl­aniline-κ2N,N′}di­chlorido­zinc di­chloro­methane hemisolvate

Acta Crystallographica Section E: Crystallographic Communications

Wile, B.M.¹ 

[1] Donald J. Bettinger Department of Chemistry and Biochemistry, Ohio Northern University, 525 S. Main Street, Ada, OH 45810, USA

关键词: CRYSTAL STRUCTURE;    IMINOPYRIDINE;    REDOX-ACTIVE LIGAND;    COORDINATION COMPOUND;    ZINC(II);    PYRIDYL HALIDE;   

DOI  :  10.1107/S2056989017007812

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate imino­pyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetra­hedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex mol­ecules and the disordered solvent mol­ecules (occupancy = 0.5), no further significant inter­molecular inter­actions are observed.

【 授权许可】

CC BY