期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of {N-[(6-bromopyridin-2-yl)(phenyl)methylidene]-2,6-dimethylaniline-κ2N,N′}dichloridozinc dichloromethane hemisolvate | |
Wile, B.M.1  | |
[1] Donald J. Bettinger Department of Chemistry and Biochemistry, Ohio Northern University, 525 S. Main Street, Ada, OH 45810, USA | |
关键词: CRYSTAL STRUCTURE; IMINOPYRIDINE; REDOX-ACTIVE LIGAND; COORDINATION COMPOUND; ZINC(II); PYRIDYL HALIDE; | |
DOI : 10.1107/S2056989017007812 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The solvated title compound, [ZnCl2(C20H17BrN2)]·0.5CH2Cl2, comprises a bidentate iminopyridine ligand and two Cl atoms bound to a zinc2+ cation in a distorted tetrahedral arrangement. The chelate bond lengths are consistent with localized C=N double bonds and a C—C single bond, as expected for an unreduced ligand bound to a closed-shell transition metal cation. Apart from weak nonclassical C—H⋯Cl hydrogen bonds between the complex molecules and the disordered solvent molecules (occupancy = 0.5), no further significant intermolecular interactions are observed.
【 授权许可】
CC BY
【 预 览 】
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