Crystal structure of (E)-5-benz­yloxy-2-{[(4-nitro­phen­yl)imino]­meth­yl}phenol

Acta Crystallographica Section E: Crystallographic Communications

Benaouida, M.A.²  Merazig, H.³  Ghichi, N.⁴  Benboudiaf, A.⁵ 

[1] Constantine 1, Algeria;de Recherche de Chimie de l'Environnement et Molédes Sciences Exactes, DéUnitéculaire Structurale (CHEMS), Facultépartement de Chimie, Université

关键词: CRYSTAL STRUCTURE;    ENOL;    IMINE;    SCHIFF BASE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015022173

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C20H16N2O4, the mol­ecule adopts an E conformation about the N=C bond. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. The nitro­benzene and benz­yloxy rings are inclined to the central benzene ring by 4.34 (10) and 27.66 (11)°, respectively, and to one another by 31.40 (12)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming zigzag chains along [001]. Within the chains there are C—H⋯π inter­actions present. The chains are linked via π–π inter­actions [inter-centroid distance = 3.7048 (15) Å], forming slabs parallel to the bc plane.

【 授权许可】

CC BY