Crystal structure of O-ethyl N-(eth­oxy­carbon­yl)thio­carbamate

Acta Crystallographica Section E: Crystallographic Communications

Schrader, A.M.¹  Barany, G.¹  Henley, M.J.¹  Young Jr, V.G.¹ 

[1] Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA

关键词: CRYSTAL STRUCTURE;    THIOCARBAMATE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015016989

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, C6H11NO3S, provides entries to novel carbamoyl disulfanes and related compounds of inter­est to our laboratory. The atoms of the central O(C=S)N(C=O)O fragment have an r.m.s. deviation of 0.1077 Å from the respective least-squares plane. While several conformational orientations are conceivable, the crystal structure shows only the one in which the carbonyl and the thio­carbonyl moieties are anti to each other across the central conjugated C—N—C moiety. Pairs of 2.54 Å N—H⋯S=C hydrogen bonds between adjacent mol­ecules form centrosymmetric dimers in the crystal.

【 授权许可】

CC BY