Crystal structure of bis­(fluoro­sulfato-κO)xenon(II), Xe(SO3F)2

Acta Crystallographica Section E: Crystallographic Communications

Malischewski, M.²  Seppelt, K.⁴ 

[1]Anorganische Chemie, Fabeckstrasse 34-36, 14195 Berlin, Germany

[2]Freie Universitä

[3]r Chemie und Biochemie –

[4]t Berlin, Institut fü

关键词: CRYSTAL STRUCTURE;    XENON;    FLUOROSULFATE;    OXIDIZER;    NOBLE GAS;    XENON-OXYGEN COMPOUND;    SUPERACID;   

DOI  :  10.1107/S2056989015004788

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

Thermally unstable Xe(SO3F)2 has been prepared by the reaction of XeF2 with HSO3F. Single crystals were obtained from HSO3F by slow cooling in a sealed tube. The mol­ecular structure is characterized by the Xe atom covalently bonded to two O atoms of two fluoro­sulfate tetra­hedra in an almost linear fashion [O—Xe—O = 179.13 (4)°]. The crystal packing is strongly influenced by inter­molecular van der Waals forces.

【 授权许可】

CC BY