Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-meth­oxy-2-oxo­ethyl­idene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclo­hex-2-enyl­idene]hydrazinyl­idene}-4-oxo­thia­zolidin-3-yl)fumarate

Acta Crystallographica Section E: Crystallographic Communications

Daran, J.-C.¹  N'ait Ousidi, A.⁴  Ait Itto, M.Y.⁶  Riahi, A.⁸  Auhmani, A.⁹ 

[1] des Sciences, Semlalia BP 2390, Marrakech 40001, Morocco;Institut de Chimie MoléLaboratoire de Chimie de Coordination, CNRS UPR8241, 205 route de Narbonne, 31077 Toulouse Cedex 04, France;Laboratoire de Physico-Chimie Moléculaire de Reims, CNRS UMR 7312 Bâculaire et Synthèdex 2, France;partement de Chimie, Facultése Organique, Dét., Europol'Agro - Moulin de la Housse UFR Sciences BP 1039-51687 Reims Cé

关键词: CRYSTAL STRUCTURE;    HETEROCYCLIC COMPOUNDS;    THIAZOLIDINE DERIVATIVES;    NATURAL PRODUCT;   

DOI  :  10.1107/S2056989017001190

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thia­zolidinone derivative prepared and isolated as pure product from thio­semicarbazone carvone. The mol­ecule is built up from an oxo­thia­zolidine ring tetra­substituted by a meth­oxy–oxo­ethyl­idene, a maleate, an oxygen and a cyclo­hexyl­idene–hydrazone. The cyclo­hexyl­idene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.

【 授权许可】

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