Crystal structure of bis­[μ-S-hexyl 3-(2-oxido­benzyl­idene)di­thio­carbazato-κ4O,N3,S:O]dicopper(II)

Acta Crystallographica Section E: Crystallographic Communications

Miyatake, R.¹  Sheikh, M.C.²  Zangrando, E.³  Begum, M.S.⁴  Howlader, M.B.H.⁴ 

[1] Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan;Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan;Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127, Trieste, Italy;Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh

关键词: CRYSTAL STRUCTURE;    SCHIFF BASE;    BINUCLEAR COPPER(II) COMPLEX;    DITHIOCARBAZATE LIGAND;   

DOI  :  10.1107/S2056989015022914

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [Cu2(C14H18N2OS2)2], is a binuclear copper(II) complex of an oxybenzyl­idenedi­thio­carbazate ligand. The ligand coordinates in a tridentate manner through N-, S- and O-donor atoms. Each O atom also bridges to a second CuII ion to form the binuclear species. It has a central Cu2O2 rhomboid moiety and a metal-to-metal separation of 2.9923 (6) Å. In the crystal, the binuclear complexes stack along the a axis with all the hexyl chains located side-by-side, forming a hydro­phobic region. The complexes are linked via C—H⋯N hydrogen bonds, forming chains along the c-axis direction. One CuII atom has the S atom of a symmetry-related complex located approximately in the apical position at 2.9740 (11) Å. This weak inter­action links the chains to form slabs parallel to the ac plane.

【 授权许可】

CC BY