Crystal structure of 5-benzoyl-2,4-di­phenyl-4,5-di­hydro­furan-3-carbo­nitrile

Acta Crystallographica Section E: Crystallographic Communications

Srinivasan, N.¹  Rajni Swamy, V.¹  Krishnakumar, R.V.¹  Sivakumar, S.²  Ranjith Kumar, R.² 

[1] Department of Physics, Thiagarajar College, Madurai 625 009, Tamil Nadu, India;School of Chemistry, Madurai Kamaraj University, Madurai 625 021, Tamil Nadu, India

关键词: CRYSTAL STRUCTURE;    FURAN;    CARBONITRILE;    HYDROGEN BOND;   

DOI  :  10.1107/S2056989015014887

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C24H17NO2, the carbonyl O atom of the benzoyl group is cis with respect to the furanyl O atom, and the associated O—C—C—O torsion angle is 4.62 (19)°. The puckering of the dihydro­furan ring is close to twisted (4T5), with parameters Q = 0.1856 (16) Å and φ = 313.5 (5)°. Mol­ecules are inter­connected via a C—H⋯N and a C—H⋯O hydrogen bond, leading to layers parallel to the (200) plane and characterized by R44(28) and R44(36) graph-set motifs. The furan O atom does not participate in inter­molecular hydrogen bonding. The crystal lattice encompasses a solvent-accessible void of 24.7 (8) Å3.

【 授权许可】

CC BY