Crystal structure of 2-[2-(hy­droxy­imino)-1-phenyl­propyl­idene]-N-phen­ylhydrazinecarbo­thio­amide

Acta Crystallographica Section E: Crystallographic Communications

Millikan, S.P.¹  Anderson, B.J.¹  Jasinski, J.P.¹  Smolenski, V.A.¹  Freedman, M.B.¹ 

[1] Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA

关键词: CRYSTAL STRUCTURE;    THIOSEMICARBAZONE;    WEAK INTERMOLECULAR INTERACTIONS;    O-H...[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989015017739

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C16H16N4OS, an intra­molecular C—H⋯S hydrogen bond is observed. With the exception of the phenyl ring of the phenyl­propyl­idene unit, the remainder of the mol­ecule has an almost planar skeleton with an r.m.s. deviation of 0.121 (5) Å from the plane through the remaining 16 atoms. In the crystal O—H⋯N hydrogen bonds are observed between the terminal hy­droxy­imino groups, forming inverson dimers with R22(6) graph-set motifs. Additional C—H⋯N contacts stack the dimers along [100]. While no π—π inter­actions are present, weak C—H⋯O and O—H⋯Cg inter­actions are also observed and help stabilize the crystal packing.

【 授权许可】

CC BY