Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of 2-hydroxy-N-(2-hydroxyethyl)-N-{2-hydroxy-3-[(E)-N-hydroxyethanimidoyl]-5-methylbenzyl}ethanaminium acetate monohydrate | |
Frost, J.M.1  Sanz, S.1  Nichol, G.S.1  Brechin, E.K.1  | |
[1] School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, Scotland | |
关键词: CRYSTAL STRUCTURE; HYDROGEN BONDING; HYDRATE; ORGANIC SALT; MAGNETISM; | |
DOI : 10.1107/S2056989015002418 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The structure of the title hydrated molecular salt, C14H23N2O4+·C2H3O2−·H2O, was determined as part of a wider study on the use of the molecule as a polydentate ligand in the synthesis of MnIII clusters with magnetic properties. The cation features intramolecular O—H⋯N and N—H⋯O hydrogen-bond interactions. The crystal structure features a range of intermolecular hydrogen-bonding interactions, principally O—H⋯O interactions between all three species in the asymmetric unit. An R24(8) graph-set hydrogen-bonding motif between the anion and water molecules serves as a unit which links to the cation via the diethanolamine group. Each O atom of the acetate anion accepts two hydrogen bonds.
【 授权许可】
CC BY
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