Crystal structure of 3-bromo-9-ethyl-9H-carbazole

Acta Crystallographica Section E: Crystallographic Communications

Bezuglyi, M.¹  Grazulevicius, J.V.²  Bagdziunas, G.²  Grybauskaite, G.² 

[1] Department of Chemistry, National Taras Shevchenko University, 62a Volodymirska st., Kyiv, Ukraine;Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu Road 19, LT-50254, Kaunas, Lithuania

关键词: CRYSTAL STRUCTURE;    CARBAZOLE;    C-H...[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989015023907

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C14H12BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH2) and 1.59 (1) Å (CH3). In the crystal, H⋯π contacts [2.698–2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine-substituted carbazole derivatives was developed.

【 授权许可】

CC BY