Crystal structure of 3-(thio­phen-2-yl)-5-p-tolyl-4,5-di­hydro-1H-pyrazole-1-carbo­thio­amide

Acta Crystallographica Section E: Crystallographic Communications

Warad, I.¹  Pavithra, G.²  Ajay Kumar, K.²  Abdoh, M.³  Lokanath, N.K.⁴  Naveen, S.⁵ 

[1] Department of Chemistry, Science College, An-Najah National University, PO Box 7, Nablus, Palestinian Territories;Department of Chemistry, Yuvaraja's College, University of Mysore, Mysore 570 006, India;Department of Physics, Science College, An-Najah National University, PO Box 7, Nablus, Palestinian Territories;Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore 570 006, India;Institution of Excellence, University of Mysore, Manasagangotri, Mysore 570 006, India

关键词: CRYSTAL STRUCTURE;    PYRAZOLE;    THIOPHENE;    CARBOTHIOAMIDE;    C-H...S HYDROGEN BONDS;    N-H...[PI] INTERACTIONS;    [PI]-[PI] INTERACTIONS;   

DOI  :  10.1107/S2056989015010774

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C15H15N3S2, the central pyrazole ring adopts a twisted conformation on the –CH—CH2– bond. Its mean plane makes dihedral angles of 7.19 (12) and 71.13 (11)° with those of the thio­phene and toluene rings, respectively. The carbothi­amide group [C(=S)—N] is inclined to the pyrazole ring mean plane by 16.8 (2)°. In the crystal, mol­ecules are linked by N—H⋯S hydrogen bonds, forming chains propagating along [010]. Within the chains, there are N—H⋯π inter­actions present. Between the chains there are weak parallel slipped π–π inter­actions involving inversion-related thio­phene and pyrazole rings [inter-centroid distance = 3.7516 (14) Å; inter-planar distance = 3.5987 (10) Å; slippage = 1.06 Å].

【 授权许可】

CC BY