Crystal structure of N′-(2,6-di­methyl­phen­yl)benzene­carboximidamide tetra­hydro­furan monosolvate

Acta Crystallographica Section E: Crystallographic Communications

Jiang, Z.-H.¹  Bai, S.-D.¹  Zhao, J.-P.¹  Liu, R.-Q.¹ 

[1] Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of China

关键词: CRYSTAL STRUCTURE;    BENZENECARBOXIMIDAMIDE;    TETRAHYDROFURAN SOLVATE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989014026255

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title compound, C15H16N2·C4H8O, contains two amidine mol­ecules (A and B) with slightly different conformations and two tetra­hydro­furan (THF) solvent mol­ecules. In the amidine mol­ecules, the di­methyl­phenyl ring and the NH2 group lie to the same side of the N=C bond and the dihedral angles between the aromatic rings are 54.25 (7) (mol­ecule A) and 58.88 (6) ° (mol­ecule B). In the crystal, N—H⋯N hydrogen bonds link the amidine mol­ecules into [100] C(4) chains of alternating A and B mol­ecules. Both amidine mol­ecules form an N—H⋯O hydrogen bond to an adjacent THF solvent mol­ecule.

【 授权许可】

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