Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure and Hirshfeld-surface analysis of (benzenecarbothioamide-κS)bromidobis(triphenylphosphane-κP)silver(I) | |
Saithong, S.1  Ruangwut, W.1  Pakawatchai, C.1  | |
[1] Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand | |
关键词: CRYSTAL STRUCTURE; AGI COMPLEX; BENZENECARBOTHIOAMIDE; TRIPHENYLPHOSPHANE; HYDROGEN BONDING; HIRSHFELD SURFACE; SUPRAMOLECULAR INTERACTION; | |
DOI : 10.1107/S2056989016009518 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The title complex, [AgBr(C7H7NS)(C18H15P)2], was obtained from the reaction of silver(I) bromide with benzenecarbothioamide (C7H7NS) and triphenylphosphane (C18H15P) in the mixed solvent of acetonitrile and ethanol. The mononuclear complex exhibits a distorted tetrahedral coordination geometry about the metal atom, arising from one S atom of a benzenecarbothioamide ligand, two P atoms of two triphenylphosphane molecules and one bromide ion. An intramolecular N—H⋯Br hydrogen bond is observed and in the crystal structure, inversion dimers linked by pairs of N—H⋯Br and C—H⋯Br hydrogen bonds are observed. In addition, C—H⋯π interactions occur, leading to [101] chains. Hirshfeld-surface analyses are presented and discussed.
【 授权许可】
CC BY
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