Crystal structure of catena-poly[[(N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide-κN1)silver(I)]-μ-nitrato-κ3O,O′:O]

Acta Crystallographica Section E: Crystallographic Communications

Kwon, E.¹  Kim, J.¹  Park, H.¹  Yoon, I.² 

[1] Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 52828, Republic of Korea;Photodynamic Therapy Research Institute, School of Nanoscience and Engineering, Inje University, 197 Injero, Gimhae, Gyeongnam 50834, Republic of Korea

关键词: CRYSTAL STRUCTURE;    CAFENSTROLE;    COORDINATION POLYMER;    SILVER;    TRIAZOLE;    HERBICIDE;   

DOI  :  10.1107/S2056989016016662

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The reaction of silver nitrate and cafenstrole (N,N-diethyl-3-mesitylsulfonyl-1H-1,2,4-triazole-1-carboxamide), a triazole herbicide, leads to the title coordination polymer, [Ag(NO3)(C16H22N4O3S)]n, whose asymmetric unit comprises one cafenstrole ligand mol­ecule, one AgI atom and one nitrate ion. The AgI atom, with a distorted trigonal–pyramidal environment, is coordinated by one nitro­gen atom of a triazole ring, two oxygen atoms of a nitrate ion and one oxygen atom of a neighboring nitrate ion. The coordination bonds between silver and oxygen atoms give rise to a one-dimensional (1D) coordination polymer structure along [001]. The dihedral angle between the planes of the triazole and benzene rings is 87.13 (11)°. In the crystal, the coordination polymer is stabilized by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in a three-dimensional architecture.

【 授权许可】

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