Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate

Acta Crystallographica Section E: Crystallographic Communications

Mehmood, B.¹  Ahmad, S.¹  Nawaz, S.¹  Nadeem, M.A.¹  Tahir, M.N.² 

[1] Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan;Department of physics, University of Sargodha, Sargodha, Punjab, Pakistan

关键词: CRYSTAL STRUCTURE;    THIOUREA;    TRIPHENYLPHOSPHANE;    SILVER(I) COMPLEX;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015001395

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the AgI atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds, generating (10-1) sheets.

【 授权许可】

CC BY