Crystal structure of the co-crystalline adduct 1,3,6,8-tetra­aza­tri­cyclo­[4.4.1.13,8]dodecane (TATD)–4-iodo­phenol (1/2): supra­molecular assembly mediated by halogen and hydrogen bonding

Acta Crystallographica Section E: Crystallographic Communications

os-Motta, J.¹  Rojas, J.J.²  Rivera, A.⁴  Bolte, M.⁵  Rí⁶ 

[1] , Có, Facultad de Ciencias, Departamento de QuíInstitut füUniversidad Nacional de Colombia, Sede Bogotádigo, Postal 111321, Colombia;mica, Cra 30 No. 45-03, Bogotár Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von Laue-Strasse 7, 60438 Frankfurt/Main, Germany

关键词: CRYSTAL STRUCTURE;    CO-CRYSTALLINE ADDUCT;    HYDROGEN BONDING;    HALOGEN BONDING;    TATD;   

DOI  :  10.1107/S2056989017014943

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title co-crystalline adduct, 1,3,6,8-tetra­aza­tri­cyclo[4.4.1.13,8]dodecane (TATD)–4-iodo­phenol (1/2), C8H16N4·2C6H5IO, comprises a half mol­ecule of the aminal cage polyamine plus a 4-iodo­phenol mol­ecule. A twofold rotation axis generates the other half of the adduct. The components are linked by two inter­molecular O—H⋯N hydrogen bonds. The adducts are further linked into a three-dimensional framework structure by a combination of N⋯I halogen bonds and weak non-conventional C—H⋯O and C—H⋯I hydrogen bonds.

【 授权许可】

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