Acta Crystallographica Section E: Crystallographic Communications | |
The silver(I) nitrate complex of the ligand N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide: a metal–organic framework (MOF) structure | |
Cati, D.S.1  Stoeckli-Evans, H.2  | |
[1] Debiopharm International S.A., Chemin Messidor 5-7, CP 5911, CH-1002 Lausanne, Switzerland;Institute of Physics, University of Neuchâtel, Switzerland;tel, rue Emile-Argand 11, CH-2000 Neuchâ | |
关键词: CRYSTAL STRUCTURE; METAL-ORGANIC FRAMEWORK; MOF; SILVER(I); PYRAZINE; CARBOXIMIDE; PYRIDINE; NITRATE; HYDROGEN BONDING; | |
DOI : 10.1107/S2056989017003930 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The reaction of silver(I) nitrate with the mono-substituted pyrazine carboxamide ligand, N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide (L), led to the formation of the title compound with a metal–organic framework (MOF) structure, [Ag(C11H10N4O)(NO3)]n, poly[μ-nitrato-[μ-N-(pyridin-2-ylmethyl-κN)pyrazine-2-carboxamide-κN4]silver(I)]. The silver(I) atom is coordinated by a pyrazine N atom, a pyridine N atom, and two O atoms of two symmetry-related nitrate anions. It has a fourfold N2O2 coordination sphere, which can be described as distorted trigonal–pyramidal. The ligands are bridged by the silver atoms forming –Ag–L–Ag–L– zigzag chains along the a-axis direction. The chains are arranged in pairs related by a twofold screw axis. They are linked via the nitrate anions, which bridge the silver(I) atoms in a μ2 fashion, forming the MOF structure. Within the framework there are N—H⋯O and C—H⋯O hydrogen bonds present.
【 授权许可】
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