N-(2-Acetamido-2-de­oxy-β-d-gluco­pyranos­yl)-N-(3-azido­prop­yl)-O-methyl­hydroxyl­amine

Acta Crystallographica Section E: Crystallographic Communications

Gainsford, G.J.¹  Munneke, S.²  Timmer, M.S.M.²  Stocker, B.L.² 

[1] Callaghan Innovation, PO Box 31-310, Lower Hutt 5040, New Zealand;School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand

关键词: CRYSTAL STRUCTURE;    OXYAMINE GLYCOSIDE;    CARBOHYDRATE;   

DOI  :  10.1107/S2056989016002164

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The structure of the title compound, C12H23N5O6, solved using adequate data from a thin crystal plate, confirmed that this useful glycoconjugate was obtained in the ring-closed β-pyran­ose configuration with 4C1 conformation. The mol­ecules are bound by O—H⋯O(OH) hydrogen bonds, notably in a zigzag C(2) chain along the short b (screw) axis, supplemented with an R22(12) O—H⋯O(carbon­yl) link along the a axis and other C(2) links. The absolute configuration was not unambiguously determined but was known from the synthetic chemistry, which used natural 2-acetamido-2-de­oxy-d-glucose as the starting material.

【 授权许可】

CC BY