期刊论文详细信息
| Green Chemistry Letters and Reviews | |
| Palladium complex in a room temperature ionic liquid: a convenient recyclable reagent for catalytic oxidation | |
| Ramakrishna Dileep1 | |
| 关键词: alcohol oxidation; Pd complexes; ionic liquid; NaOCl; | |
| DOI : 10.1080/17518253.2014.891660 | |
| 学科分类：化学（综合） | |
| 来源: Taylor & Francis | |
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【 摘 要 】
Palladium (Pd)-catalyzed carbonylation of alcohols proceeds in ionic liquid (IL) media (1-ethyl-3-methylimidazolium hexafluorophosphate). Carbonylation of primary/secondary alcohols to aldehydes/ketones was greatly accelerated by the use of a Pd-based catalyst in the presence of NaOCl as an oxidant. The catalyst was more easier to recycle in the IL [Emim]PF6 with an equal-proportioned CH2Cl2 than in the single CH2Cl2 or IL.
【 授权许可】
Unknown
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO201904030686089ZK.pdf | 2500KB |  download |
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