期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of 2-methoxy-2-[(4-methylphenyl)sulfanyl]-1-phenylethan-1-one | |
Zukerman-Schpector, J.2  a, J.3  Olivato, P.R.4  Rodrigues, D.N.S.5  Traesel, H.J.6  Valenç7  Tiekink, E.R.T.8  | |
[1] Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia;Departmento de QuíInstituto de Química, Universidade Federal de Sãmica, Universidade de São Carlos, 13565-905 São Carlos, SP, Brazil;o Paulo, 05508-000 São Paulo, SP, Brazil | |
关键词: CRYSTAL STRUCTURE; [BETA]-THIOCARBONYL; C-H...O INTERACTIONS; | |
DOI : 10.1107/S205698901402550X | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
In the title β-thiocarbonyl compound, C16H16O2S, the carbonyl and methoxy O atoms are approximately coplanar [O—C—C—O torsion angle = −18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supramolecular chains are formed along the c axis mediated by C—H⋯O interactions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific intermolecular interactions between them.
【 授权许可】
CC BY
【 预 览 】
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