期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN2){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ3O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1) | |
Du, C.-J.1  Zhao, X.-N.1  | |
[1] School of Biochemical and Chemical Engineering, Nanyang Institute of Technology, Nanyang 473000, People's Republic of China | |
关键词: CRYSTAL STRUCTURE; COII COMPLEX; AMINOPHOSPHONATE; ORGANOPHOSPHORUS MATERIALS; FLAME RETARDANTS; | |
DOI : 10.1107/S2056989017015079 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
In the title compound, [Co(C11H12NO6P)(C6H5N3)2]·C6H5N3, the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianion N,O,O′,O′′-chelates the CoII cation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the CoII cation to complete the slightly distorted octahedral coordination. In the crystal, classical O—H⋯O, N—H⋯O hydrogen bonds and weak C—H⋯N hydrogen bonds link the molecules into a three-dimensional supramolecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.
【 授权许可】
CC BY
【 预 览 】
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