Crystal structure of [μ2-1,1′-bis­(di­phenyl­phos­phanyl)ferrocene-κ2P:P′]bis­[(pyrrolidine-1-carbo­dithioato-κS)gold(I)]

Acta Crystallographica Section E: Crystallographic Communications

Tan, Y.S.¹  Tiekink, E.R.T.¹ 

[1]Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

关键词: CRYSTAL STRUCTURE;    GOLD(I);    PHOSPHANE;    DITHIOCARBAMATE;   

DOI  :  10.1107/S2056989015016382

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title compound, {(C34H28FeP2)[Au(C5H8NS2)]2}, comprises half a mol­ecule, with the full mol­ecule being generated by the application of a centre of inversion. The independent AuI atom is coordinated by thiol­ate S and phosphane P atoms that define an approximate linear geometry [S—Au—P = 169.35 (3)°]. The deviation from the ideal linear is traced to the close approach of the (intra­molecular) non-coordinating thione S atom [Au⋯S = 3.1538 (8) Å]. Supra­molecular layers parallel to (100) feature in the crystal packing, being sustained by phen­yl–thione C—H⋯S inter­actions, with the non-coordinating thione S atom in the role of a dual acceptor. Layers stack with no specific inter­actions between them.

【 授权许可】

CC BY