Metal–organic frameworks for H2 and CH4 storage: insights on the pore geometry–sorption energetics relationship

IUCrJ

Belmabkhout, Y.¹  Cairns, A.¹  Alkordi, M.H.¹  Eddaoudi, M.¹ 

[1]Division of Physical Sciences and Engineering, Advanced Membranes and Porous Materials Center, Functional Materials Design, Discovery and Development Research Group (FMD3), King Abdullah University of Science and Technology (KAUST), Thuwal 4700, Saudi Arabia

关键词: TAILORED PORE GEOMETRY;    METAL-ORGANIC FRAMEWORKS;    MOFS;    HYDROGEN STORAGE;    DISPERSIVE INTERACTIONS;   

DOI  :  10.1107/S2052252516019060

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

This study aims to assess the possibility of improving H2 and CH4 binding affinity to the aromatic walls of a designed new Metal–Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

【 授权许可】

CC BY