Crystal structure of Li3Ga(BO3)2

Acta Crystallographica Section E: Crystallographic Communications

Villa, E.M.¹  Smith, R.W.²  Holman, D.² 

[1] Department of Chemistry, Creighton University, 2500 California Plaza, Omaha, Nebraska 68178, USA;Department of Chemistry, University of Nebraska at Omaha, 6001 Dodge Street, Omaha, Nebraska 68182, USA

关键词: CRYSTAL STRUCTURE;    CRYSTAL DIFFRACTION;    GALLIUM;    BORATE;   

DOI  :  10.1107/S205698901700295X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The crystal structure of trilithium gallium bis­(orthoborate), Li3Ga(BO3)2, is isotypic with Li3Al(BO3)2 in a triclinic cell in space-group type P-1. The three Li and the unique Ga atom are coordinated by four O atoms each in tetra­hedra, and the two B atoms are coordinated by three O atoms in orthoborate triangles. Chains with composition [Ga2(BO3)4]6− extend along the a axis. The Li atoms inter­leave these chains in tetra­hedral inter­stices. A comparison is made between the structure model of the title compound and that of a previously reported model for a compound with the same composition [Abdullaev & Mamedov (1972). Zh. Strukt. Khim. 13, 943–946.]

【 授权许可】

CC BY