Bis(μ2-N-methyl-N-phenyl­dithio­carbamato)-κ3S,S′:S;κ3S:S,S′-bis­[(N-methyl-N-phenyl­dithio­carbamato-κ2S,S′)cadmium]: crystal structure and Hirshfeld surface analysis

Acta Crystallographica Section E: Crystallographic Communications

Suwardi, S.A.N.¹  Jotani, M.M.²  Lee, S.M.³  Tiekink, E.R.T.³  Lo, K.M.³ 

[1] Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia;Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380 001, India;Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

关键词: CRYSTAL STRUCTURE;    CADMIUM;    DITHIOCARBAMATE;    HIRSHFELD SURFACE ANALYSIS;   

DOI  :  10.1107/S2056989017002705

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di­thio­carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter­mediate between square-pyramidal and trigonal–bipyramidal, but tending towards the former. The packing features C—H⋯S and C—H⋯π inter­actions, which generate a three-dimensional network. The influence of these inter­actions, along with intra-dimer π–π inter­actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

【 授权许可】

CC BY