Crystal structure of the η4-ketimine titanium complex (di­phenyl­amido-κN){3-methyl-6-[(4-methyl­phen­yl)(phenyl­aza­nid­yl)methyl­idene]cyclo­hexa-2,4-dien-1-yl-κ2N,C1}(η5-penta­methyl­cyclo­penta­dien­yl)titanium(IV)

Acta Crystallographica Section E: Crystallographic Communications

Fischer, M.¹  Schmidtmann, M.¹  Beckhaus, R.¹ 

[1]Institut für Chemie, Fakultät für Mathematik und Naturwissenschaften, Carl von Ossietzky Universität Oldenburg, 26129 Oldenburg, Germany

关键词: CRYSTAL STRUCTURE;    TITANIUM;    [ETA]4-KETIMINE COMPLEX;    HALF-SANDWICH COMPLEX;   

DOI  :  10.1107/S2056989017017455

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate di­phenyl­amide ligand. Except for van der Waals forces, there are no significant inter­molecular inter­actions in the crystal.

【 授权许可】

CC BY