Crystal structure of (OC)5W(μ-dppe)W(CO)5

Acta Crystallographica Section E: Crystallographic Communications

Wheeler, K.A.¹  Drake, H.F.²  Bellott, B.J.² 

[1] Department of Chemistry, Eastern Illinois University, Charleston, Illinois, 61920, USA;Department of Chemistry, Western Illinois University, Macomb, Illinois 61455, USA

关键词: CRYSTAL STRUCTURE;    GROUP 6 CARBONYL;    BRIDGING DPPE;    BIMETALLIC;   

DOI  :  10.1107/S2056989016013670

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di­phenyl­phosphane)-κ2P:P′]bis­[penta­carbonyl­tungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis­(di­phenyl­phosphan­yl)ethane (dppe) ligand. The W0 atom has a slightly distorted octa­hedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W0 atom 5.625 (5) Å away. The complex resides on a center of symmetry.

【 授权许可】

CC BY