Crystal structure of (2Z,5Z)-3-(4-meth­oxy­phen­yl)-2-[(4-meth­oxy­phenyl)­imino]-5-[(E)-3-(2-nitro­phen­yl)allyl­idene]-1,3-thia­zolidin-4-one

Acta Crystallographica Section E: Crystallographic Communications

Daran, J.-C.¹  Djafri, A.²  Rahmani, R.³  Chouaih, A.³  Hamzaoui, F.³ 

[1] Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse Cedex, France;Laboratoire de Synthèse Organique Appliquée (LSOA), Département de Chimie, Faculté de Sciences, University of Oran Es-Sénia, 31000 Oran, Algeria;Laboratory of Technology and Properties of Solids, Abdelhamid Ibn Badis University, BP 227 Mostaganem 27000, Algeria

关键词: CRYSTAL STRUCTURE;    THIAZOLIDINONE;    HYDROGEN BONDING;    [PI]-[PI] STACKING;   

DOI  :  10.1107/S2056989016000207

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, C26H21N3O5S, the thia­zole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions link the mol­ecules into a three-dimensional supra­molecular architecture. Aromatic π–π stacking is also observed between the parallel nitro­benzene rings of neighbouring mol­ecules, the centroid-to-centroid distance being 3.5872 (15) Å.

【 授权许可】

CC BY