Crystal structure of 5,15-bis­(4-methyl­phen­yl)-10,20-bis­(4-nitro­phen­yl)porphyrin nitro­benzene disolvate

Acta Crystallographica Section E: Crystallographic Communications

Baptayev, B.¹  Adilov, S.¹ 

[1] National Laboratory Astana, Laboratory of Chemistry, Nazarbayev University, 53 Kabanbay Batyr Ave, Astana, 010000, Kazakhstan

关键词: CRYSTAL STRUCTURE;    PORPHYRINS;    SOLVATE;    C-H...O HYDROGEN BONDING;   

DOI  :  10.1107/S2056989017017868

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The whole mol­ecule of the title porphyrin, C46H32N6O4·2C6H5NO2, which crystallized as a nitro­benzene disolvate, is generated by inversion symmetry. The porphyrin macrocycle is almost planar, the maximum deviation from the mean plane of the non-hydrogen atoms is 0.097 (2) Å. The aryl rings at the meso positions are inclined to this mean plane by 74.84 (6)° for the nitro­phenyl rings and 73.37 (7)° for the tolyl rings. In the crystal, the porphyrin mol­ecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. The solvent mol­ecules are also linked by C—H⋯O hydrogen bonds, forming chains along [100]. Inter­digitation of the p-tolyl groups along the c axis creates rectangular channels in which the solvent mol­ecules are located.

【 授权许可】

CC BY