Rapid and simultaneous determination of tetrabromobisphenol A and hexabromocyclododecane diastereoisomers in soil by matrix solid-phase dispersion with bamboo charcoal as dispersive adsorbent

Acta Chromatographicae

Cheng Chuan-Ge¹  Wang Shan-Shan¹  Li Fu-Wei¹  Song Xin-Li¹  Wang Xiao-Li¹  Yuan Jin-Peng²  Cui Zhao-Jie³ 

[1] 1Shandong Provincial Key Laboratory of Applied Technology of Sophisticated Analytical Instruments, Analysis and Test Center, Shandong Academy of Sciences, Jinan 250014, China;1Shandong Provincial Key Laboratory of Applied Technology of Sophisticated Analytical Instruments, Analysis and Test Center, Shandong Academy of Sciences, Jinan 250014, China2School of Environmental Science and Engineering, Shandong University, Jinan 250100, ChinaAuthor for correspondence: [e-mail];2School of Environmental Science and Engineering, Shandong University, Jinan 250100, China

关键词: Tetrabromobisphenol A;    hexabromocyclododecane diastereoisomers;    matrix solid-phase dispersion;    bamboo charcoal;    soil;   

DOI  :  10.1556/1326.2016.00122

学科分类：化学（综合）

来源: Akademiai Kiado Rt.

【 摘 要 】

A rapid and simple analytical method based on matrix solid-phase dispersion combined with liquid chromatography coupled with tandem mass spectrometry has been developed by using bamboo charcoal as a dispersive adsorbent to simultaneously determine tetrabromobisphenol A (TBBPA) and hexabromocyclododecane diastereoisomers (HBCDs) in soil. The factors influencing the performance of the proposed method were investigated and optimized in detail, and the matrix effects were evaluated. Under optimum conditions, the proposed method showed good linearity within the range of 0.8–80 ng g−1 and limits of detection of 4–75 pg g−1 (S/N = 3). The satisfactory recoveries of TBBPA ranging from 72.8% to 92.5% and HBCDs ranging from 76.8% to 102.2% were obtained with relatively standard deviation (RSD) ranging from 3.4% to 9.8%. The proposed method has been successfully applied to analyze TBBPA and HBCDs in actual soil samples from the Yellow River Delta in China.

【 授权许可】

Unknown