Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ2N,O}(1,10-phenanthroline-κ2N,N′)nickel(II)

Acta Crystallographica Section E: Crystallographic Communications

Faizi, M.S.H.¹  Malinkin, S.²  Dege, N.³ 

[1] Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of Oman;Department of Chemistry, National Taras Shevchenko University of Kiev, 64/13, Volodymyrska Street, City of Kyiv, 01601, Ukraine;Ondokuz May?s University, Arts and Sciences Faculty, Department of Physics, 55139 Atakum–Samsun, Turkey

关键词: CRYSTAL STRUCTURE;    NICKEL(II);    PHENANTHROLINE;    AMINE;    LEUCINE;    SALICYLALDEHYDE;    C-H...[PI] INTERACTIONS;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989017012014

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [Ni(C13H18NO3)2(C12H8N2)], the NiII cation shows a distorted octa­hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy­droxy­benz­yl)amino]-4-methyl­penta­noate ligands. Complex mol­ecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxyl­ate and phenoxide groups, which are further connected into a three-dimensional motif.

【 授权许可】

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