Determination of nitrite in water using a flower extract

Quimica nova

Cavalheiro, Carla Cristina Schmitt¹  Ramos, Luiz Antônio¹  Cavalheiro, Éder Tadeu Gomes¹ 

[1] Universidade de São Paulo, São Carlos

关键词: acid-base chemistry;    instrumental methods;    water/water chemistry.;   

DOI  :  10.1590/S0100-40422006000500037

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

Aspects of visiblespectrophotometry can be presented to students using simple experiments in whichthe color of the crude extract of Macroptilium lathyroides (L.) Urb.is bleached in the presence of nitrite ions in acidic medium. The dependenceof the absorption intensity with time, the reaction completeness and the Beerlaw can be demonstrated. Quantitative results for mineral water samples "contaminated"with nitrite ions were obtained from a method based on the Griess reaction anda procedure based on the bleaching reaction between the crude extract and NO2-ions. Both the Griess and the bleaching reactions were found to be time dependent.Recoveries of about 100 - 104% were obtained with these procedures. The useof natural dyes attracted students' interest enhancing the teaching process.Experiments performed by the teaching staff suggested that the proposed methodologycan be performed in a 4 h class, with relative errors ranging from 0.19 to 1.86%in relation to the Griess method.

【 授权许可】

CC BY