Utilization of the solid amalgam electrodes in the analytical determination of organic and inorganic compounds

Quimica nova

Mascaro, Lucia Helena¹  Fatibello-Filho, Orlando¹  Correia, Adriana Nunes²  Melo, Luisa Célia²  Lima-Neto, Pedro de²  Souza, Djenaine de² 

[1] Universidade Federal de São Carlos, São Carlos, Brasil;Universidade Federal do Ceará, Fortaleza, Brasil

关键词: solid amalgam electrodes;    mercury;    environmentally friendly sensor.;   

DOI  :  10.1590/S0100-40422011000300022

学科分类：化学（综合）

来源: Sociedade Brasileira de Quimica

【 摘 要 】

This review reportsthe use of solid amalgam electrodes in the electroanalytical determination oforganic and inorganic compounds. The different types of amalgam electrodes arepresented, and attention is paid to solid amalgam electrode, and here is presenteddetails about the pre-treatment for activation and renovation and also possiblemodifications in its surface. The wide potential range, higher signal-to-noiseratio, mechanical stability enabling their application in flowing systems, andprincipally their resistance toward passivation, indicate that the solid amalgamelectrodes are environmentally friendly alternatives to mercury electrodes,without loss in the sensitivity and reproducibility in voltammetric responses.

【 授权许可】

CC BY