A NEW METHOD FOR ONE-POT SYNTHESIS OF ARYLOXYPHENOXYPROPIONATE HERBICIDES USING 2,4,6-TRICHLORO-1,3,5-TRIAZINE AND (n-BU)4NI AS A HOMOGENEOUS CATALYST

Journal of The Chilean Chemical Society

MOBINIKHALEDI, AKBAR¹  TAJIK, HASSAN²  DADRAS, AKBAR³  KALHOR, MEHDI⁴ 

[1] Arak University, Arak, Iran;Guilan University, Rasht, Iran;Islamic Azad University, Qiamdasht, Iran;Payame Noor University, Tehran, Iran

关键词: One-;    pot reaction;    Catalyst;    Aryloxyphenoxy propionate;    Cyanuric chloride;   

DOI  :  10.4067/S0717-97072011000400002

学科分类：化学（综合）

来源: Sociedad Chilena de Quimica

【 摘 要 】

The one-pot reaction of halo-heterocycle, (R)-4-hydroxyphenoxy propionic acid and an alcohol, amine or sulfonamide is described as an efficient method for the synthesis of aryloxyphenoxy propionate hrerbicides by using 2,4,6-trichloro-1,3,5-triazine in the presence of (n-BU)4NI, as a homogeneous catalyst under mild conditions. The present procedure offers several advantages, such as good yields, short reaction times and easy workup.

【 授权许可】

Unknown