Crystal structure of Ba5In4Sb6

Acta Crystallographica Section E: Crystallographic Communications

Pan, M.-Y.¹  Xia, S.-Q.¹  Tao, X.-T.¹ 

[1] State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100, People's Republic of China

关键词: CRYSTAL STRUCTURE;    BARIUM;    INDIUM;    ANTIMONY;    IN-IN INTERCONNECTIONS;   

DOI  :  10.1107/S2056989015006933

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, penta­barium tetra­indium hexa­anti­mony, was synthesized by an indium-flux reaction and its structure features layers composed of edge-sharing In2Sb6 units. The voids between the In4Sb6 layers are filled by Ba2+ cations, which are all surrounded by six Sb atoms and form bicapped octa­hedral or triangular prismatic coordination geometries. There are five barium ions in the asymmetric unit: one has no imposed crystallographic symmetry, two lie on mirror planes and two have mm2 point symmetry. The two In atoms and four Sb atoms in the asymmetric unit all lie on general crystallographic positions.

【 授权许可】

CC BY