Crystal structure of tri­chlorido­(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)iridium(III) aceto­nitrile disolvate

Acta Crystallographica Section E: Crystallographic Communications

Davaasuren, B.¹  Padhy, H.¹  Rothenberger, A.¹ 

[1] Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, KAUST, Thuwal 23955-6900, Kingdom of , Saudi Arabia

关键词: CRYSTAL STRUCTURE;    IRIDIUM;    4'-FERROCENYL-2,2':6',2''-TERPYRIDINE;   

DOI  :  10.1107/S2056989015003473

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [FeIr(C5H5)(C20H14N3)Cl3]·2CH3CN, the central IrIII atom is sixfold coordinated by three chloride ligands and three terpyridine N atoms in a slightly distorted octa­hedral fashion. The terpyridine ligand is functionalized at the 4′-position with a ferrocenyl group, the latter being in an eclipsed conformation. In the crystal, mol­ecules are stacked in rows parallel to [001], with the aceto­nitrile solvent mol­ecules situated between the rows. An extensive network of intra- and inter­molecular C—H⋯Cl inter­actions is present, stabilizing the three-dimensional structure.

【 授权许可】

CC BY