Crystal structure of tetrakis­(acetyl­acetonato)di­chloridodi-μ3-methano­lato-tetra-μ2-methano­lato-tetra­iron(III)

Acta Crystallographica Section E: Crystallographic Communications

Gray, D.L.¹  Richers, C.P.¹  Bertke, J.A.¹  Rauchfuss, T.B.¹ 

[1] School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA

关键词: CRYSTAL STRUCTURE;    CLUSTER;    IRON(III);    ACETYLACETONATE;    OUBLE CUBANE;   

DOI  :  10.1107/S2056989015013535

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetyl­acetonate), crystallizes in the ortho­rhom­bic Pbca space group with one half of the mol­ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubaneentity with two opposite corners missing. Weak C—H⋯Cl inter­molecular inter­actions result in a two-dimensional layered structure parallel to the ac plane.

【 授权许可】

CC BY