Crystal structure of bis­(μ-2-benzoyl­benzoato-κ2O:O′)bis­[bis­(2,2′-bi­pyridine-κ2N,N′)manganese(II)] bis­(perchlorate)

Acta Crystallographica Section E: Crystallographic Communications

Kani, I.¹ 

[1] Anadolu University, Faculty of Sciences, Department of Chemistry, 26470 Eskişehir, Turkey

关键词: CRYSTAL STRUCTURE;    MANGANESE(II) COMPLEX;    BENZOYLBENZOATE;    2,2'-BIPYRIDINE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015023671

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [Mn2(C6H5COC6H4COO)2(C10H8N2)4](ClO4)2, comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two MnII atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each MnII atom being further coordinated by two 2,2′-bi­pyridine (bipy) ligands in a distorted octa­hedral environment. Within the binuclear mol­ecule, the Mn⋯Mn separation is 4.513 (7) Å. Inter­molecular C—H⋯O and C—H⋯ π inter­actions link the mol­ecules into a three-dimensional network.

【 授权许可】

CC BY