Two-Photon Absorption Cross Sections of Dithienothiophene-Based Molecules

ETRI Journal

关键词: optical limiting;    Two-photon absorption;   

Others  :  1184580
DOI  :  10.4218/etrij.02.0102.0306

【 摘 要 】

We performed nonlinear transmission measurements and quantum-chemical calculations on dithienothiophene (DTT)-based molecules to gain insight into the effect of acceptor and donor groups on two-photon absorption (TPA) properties. The TPA intensity showed

   

【 参考文献 】

• [1]M. Goppert-Mayer, "Uber Elementarakte mit zwei Quantens prungen," Ann. Phys., vol. 9, 1931, pp. 273-295.
• [2]W. Denk, J.H. Strickler, and W.W. Webb, "Two-Photon Laser Scanning Fluorescence Microscopy," Science, vol. 248, 1990, pp. 73-76.
• [3]D.A. Parthenopoulos and P.M. Rentzepis, "Three-Dimensional Optical Storage Memory," Science, vol. 245, 1989, pp. 843-845.
• [4]E.H.K. Stelzer, S. Hell, R. Stricker, R. Pick, C. Storz, G. Ritter, and N. Salmon, "Nonlinear Absorption Extends Confocal Fluorescence Microscopy into the Ultraviolet Regime and Confines the Illumination Volume," Optical Comm., vol. 104, 1994, pp. 223-228
• [5]G.S. He, R. Gvishi, P.N. Prasad, and B.A. Reinhardt, "Two-Photon Absorption Based Optical Limiting and Stabilization in Organic Molecule-Doped Solid Materials," Optical Comm., vol. 117, 1995, pp. 133-136.
• [6]J. Oberle, L. Bramerie, G. Jonusauskas, and C. Rulliere, "Optical-Limiting Properties of a Push-Pull Diphenyl-Butadiene," Optical Comm., vol. 169, 1999, pp. 325-332.
• [7]S. Maruo, O. Nakamura, and S. Kawata, "Three-Dimensional Microfabrication with Two-Photon-Absorbed Photopolym- erization," Optical Lett., vol. 22, 1997, pp. 132-134.
• [8]O.-K. Kim, A. Fort, M. Barzoukas, M. Blanchard-Desce, and J.-M. Lehn, "Nonlinear Optical Chromophores Containing Dithienothiophene as a New Type of Electron Relay," J. Mater. Chem., vol. 9, 1999, pp. 2227-2230.
• [9]O.K. Kim, K.-S. Lee, H.Y. Woo, K.S. Kim, G.S. He, J. Swiatkiewicz, and P.N. Prasad, "New Class of Two-Photon-Absorbing Chromophores Based on Dithienothiophene," Chem. Mater., vol. 12, 2000, pp. 284-286.
• [10]J.E. Ehrlich, X.L. Wu, I.-Y.S. Lee, Z.-H. Hu, H. Rockel, S.R. Marder, and J.W. Perry, "Two-Photon Absorption and Broadband Optical Limiting with Bis-Donor Stilbenes," Optical Lett., vol. 22, 1997, pp. 1843-1845.
• [11]M. Albota, D. Beljonne, J.-L. Bredas, J.E. Ehrlich, J.-Y. Fu, A.A. Heikal, S.E. Hess, T. Kogej, M.D. Levin, S.R. Marder, D. McCord-Maughon, J.W. Perry, H.R.M. Rumi, G. Subramaniam, W.W. Webb, X.-L. Wu, and C. Xu, "Design of Organic Molecules with Large Tw
• [12]N. Mukherjee, A. Mukherjee, and B.A. Reinhardt, "Measurement of Two-Photon Absorption cross Sections of Dye Molecules Doped in Thin Films of Polymethylmethacrylate," Applied Physics Lett., vol. 70, 1997, pp. 1524-1526.
• [13]C.-K. Wang, P. Macak, Y. Luo, and H. Agren, "Effects of Centers and Symmetry on Two-Photon Absorption cross Sections of Organic Chromophores," J. Chem. Phys., vol. 114, 2001, pp. 9813-9820.