期刊论文详细信息
Sustainable Chemical Processes
Microwave energy potential for biodiesel production
Veera Gnaneswar Gude2  Prafulla Patil3  Edith Martinez-Guerra2  Shuguang Deng3  Nagamany Nirmalakhandan1 
[1] Civil and Environmental Engineering Department, New Mexico State University, Las Cruces, NM, 88003, USA
[2] Civil and Environmental Engineering Department, Mississippi State University, Mississippi State, MS, 39762, USA
[3] Chemical Engineering Department, New Mexico State University, Las Cruces, NM, 88003, USA
关键词: Ultrasonics;    Large scale production;    Process optimization;    Microwaves;    Biodiesel;   
Others  :  789189
DOI  :  10.1186/2043-7129-1-5
 received in 2013-02-27, accepted in 2013-04-18,  发布年份 2013
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【 摘 要 】

Microwave energy based chemical synthesis has several merits and is important from both scientific and engineering standpoints. Microwaves have been applied in numerous inorganic and organic chemical syntheses; perhaps, from the time their ability to work as heat source was discovered. Recent laboratory scale microwave applications in biodiesel production proved the potential of the technology to achieve superior results over conventional techniques. Short reaction time, cleaner reaction products, and reduced separation-purification times are the key observations reported by many researchers. Energy utilization and specific energy requirements for microwave based biodiesel synthesis are reportedly better than conventional techniques. Microwaves can be very well utilized in feedstock preparation, extraction and transesterification stages of the biodiesel production process. Although microwave technology has advanced in other food, pharmaceutical and polymer chemistry related research and industry, it has yet to prove its potential in the biodiesel industry at large scale applications. This paper reviews principles and practices of microwave energy technology as applied in biodiesel feedstock preparation and processing. Analysis of laboratory scale studies, potential design and operation challenges for developing large scale biodiesel production systems are discussed in detail.

【 授权许可】

   
2013 Gude et al.; licensee Chemistry Central Ltd.

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【 参考文献 】
  • [1]Satyanarayana KG, Mariano AB, Vargas JVC: A review on microalgae, a versatile source for sustainable energy and materials. Int J Energy Res 2011, 35:291-311.
  • [2]Demirbas A: Global renewable energy projections. Energy Sources, Part B 2009, 4:212-224.
  • [3]Rittmann RE: Opportunities for renewable bioenergy using microorganisms. Biotechnol Bioengr 2008, 100:203-212.
  • [4]Fabbri D, Bevoni V, Notari M, Rivetti F: Properties of a potential biofuel obtained from soybean oil by transmethylation with dimethyl carbonate. Fuel 2007, 86:690-697.
  • [5]Pimentel D: Biofuels, solar and wind as renewable energy systems. New York: Springer Science + Business Media B.V; 2008.
  • [6]Energy independence and security act of 2007: summary of provisions http://www.eia.gov/oiaf/aeo/otheranalysis/aeo_2008analysispapers/eisa.html webcite
  • [7]Georgogianni KG, Kontominas MG, Tegou E, Avlonitis D, Gergis V: Biodiesel production: reaction and process parameters of alkali-catalyzed transesterification of waste frying oils. Energy & Fuels 2007, 21:3023-3027.
  • [8]Yang J, Xu M, Zhang X, Hu Q, Sommerfeld M, Chen Y: Life-cycle analysis on biodiesel production from microalgae: water footprint and nutrients balance. Bioresour Technol 2011, 102:159-165.
  • [9]Hoekman SK: Biofuels in the U.S. - challenges and opportunities. Renewable Energy 2009, 34:14-22.
  • [10]Kargbo DM: Biodiesel production from municipal sewage sludges. Energy Fuels 2010, 24(5):2791-2794.
  • [11]Haas MJ, McAloon AJ, Yee WC, Foglia TA: A process model to estimate biodiesel production costs. Bioresource Technology 2006, 97:671-678.
  • [12]Cintas P, Mantegna S, Gaudino EC, Cravotto G: A new pilot flow reactor for high-intensity ultrasound irradiation. Application to the synthesis of biodiesel. Ultrasonics Sonochemistry 2010, 17:985-989.
  • [13]Harvey AP, Mackley MR, Seliger T: Process intensification of biodiesel production using a continuous oscillatory flow reactor. J Chem Technol Biotechnol 2003, 78:338-341.
  • [14]Clark DE, Sutton WH: Microwave processing of materials. Annual Review of Materials Science 1996, 26:299-331.
  • [15]Caddick S, Fitzmaurice R: Microwave enhanced synthesis. Tetrahedron 2009, 65:3325-3355.
  • [16]Ku HS, Siores E, Taube A, Ball JAR: Productivity improvements through the use of industrial microwave technologies. Computers & Industrial Engineering 2002, 42(2–4):281-290.
  • [17]de la Hoz A, Diaz-Ortiz A, Moreno A: Microwaves in organic synthesis. Thermal and non-thermal microwave effects. Chem Soc Rev 2005, 34:164-178.
  • [18]Roberts B, Strauss CR: Toward rapid, “green”, predictable microwave-assisted synthesis. Acc Chem Res 2005, 38:653-661.
  • [19]Varma RS: Solvent- free organic syntheses using supported reagents and microwave irradiation. Green Chem 1999, 1:43-55.
  • [20]Giguere RJ, Bray TL, Duncan SM, Majetich G: Application of commercial microwave ovens to organic synthesis. Tetrahedron Lett 1986, 27:4945-4948.
  • [21]Stuerga D, Delmotte M: Microwaves in Organic Synthesis. Edited by Loupy A. Wiley-VCH Weinheim; 2002:1-34.
  • [22]Mingos DMP: Microwave-assisted organic synthesis. Edited by Lidstrom P, Tierney JP. Oxford: Blackwell; 2004. Chap. 1
  • [23]Baghurst DR, Mingos DMP: Applications of microwave dielectric heating effects to the synthetic problems in chemistry. Chem Soc Rev 1991, 20:1-47.
  • [24]Gabriel C, Gabriel S, Grant EH, Halstead BS, Mingos DMP: Dielectric parameters relevant to microwave dielectric heating. Chem Soc Rev 1998, 27:213-223.
  • [25]Developments on microwave chemistry. 2005. [Intellectual property report. Evaluserve analysis] http://www.rsc.org/images/evaluserve_tcm18-16758.pdf webcite
  • [26]Metaxas AC, Meredith RJ: Industrial microwave heating. London: Peter Peregrinus Ltd; 1993.
  • [27]Peterson ER: Microwave chemical processing. Res Chem Intermed 1994, 1:93-96.
  • [28]Chemat-Djenni Z, Hamada B, Chemat F: Atmospheric pressure microwave assisted heterogeneous catalytic reactions. Molecules 2007, 12:1399-1409.
  • [29]Varma RS: Solvent-free accelerated organic syntheses using microwaves. Pure and Applied Chemistry 2001, 73(1):193-198.
  • [30]Refaat AA: Different techniques for the production of biodiesel from waste vegetable oil. Int J Environ Sci Tech 2010, 7(1):183-213.
  • [31]Bogdal D: Microwave-assisted organic synthesis. Elsevier Ltd; 2005.
  • [32]Groisman Y, Gedanken A: Continuous flow, circulating microwave system and its application in Nanoparticle fabrication and biodiesel synthesis. J Phys Chem C 2008, 112:8802-8808.
  • [33]Kappe CO: The impact of microwave synthesis on drug discovery. Nat Rev Drug Discov. 2006, 5:51-63.
  • [34]Li Y, Yang W: Microwave synthesis of zeolite membranes: a review. J Membrane Sci 2008, 316:3-17.
  • [35]Kappe CO: Controlled microwave heating in modern organic synthesis. Angew Chem. Int. Ed. 2004, 43:6250-6284.
  • [36]Herrero MA, Kremsner JM, Kappe CO: Nonthermal microwave effects revisited: on the importance of internal temperature monitoring and agitation in microwave chemistry. J Org Chem 2008, 73:36-47.
  • [37]Maher KD, Bressler DC: Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. Bioresour Technol 2007, 98:2351-2368.
  • [38]Hoekman SK: Biofuels in the U.S.-challenges and opportunities. Renewable Energy 2009, 34:14-22.
  • [39]Sharma YC, Singh B, Upadhyay SN: Advancements in development and characterization of biodiesel: a review. Fuel 2008, 87:2355-2373.
  • [40]Akoh CC, Chang S, Lee G, Shaw JJ: Enzymatic approach to biodiesel production. J Agric Food Chem 2007, 55:8995-9005.
  • [41]Kusdiana D, Saka S: Two-step preparation for catalyst-free biodiesel fuel production. Appl Biochem Biotechnol 2004, 113–116:781-791.
  • [42]Freedman B, Pryde EH, Mounts TL: Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Oil Chem Soc 1984, 61(10):1638-1643.
  • [43]Srivastava A, Prasad R: Triglycerides-based diesel fuels. Renewable & Sustainable Energy Rev 2000, 4(2):111-133.
  • [44]Kaieda M, Samukawa T, Kondo A, Fukuda H: Effect of methanol and water contents on production of biodiesel fuel from plant oil catalyzed by various lipases in a solvent-free system. J Biosci and Bioengr 2001, 91(1):12-15.
  • [45]Komers K, Stloukal R, Machek J, Skopal F: Biodiesel from rapeseed oil, methanol and KOH 3: analysis of composition of actual reaction mixture. Eur J Lipid Scie Technol 2001, 103(6):363-371.
  • [46]Zhang Y, Dube MA, Mclean DD, Kates M: Biodiesel production from waste cooking oil. 1. Process design and technological assessment. Bioresour Technol 2003, 89(1):1-16.
  • [47]Suppes GJ, Dasari MA, Doskocil EJ, Mankidy PJ, Goff MJ: Transesterification of soybean oil with zeolite and metal catalysts. Applied Catalysis A: General 2004, 257(2):213-223.
  • [48]Haas MJ, McAloon AJ, Yee WC, Foglia TA: A process model to estimate biodiesel production costs. Bioresour Technol 2006, 97:671-678.
  • [49]Meher LC, Sagar DV, Naik SN: Technical aspects of biodiesel production by transesterification: a review. Renewable Sustainable Energy Reviews 2006, 10(3):248-268.
  • [50]Patil PD, Deng S: Optimization of biodiesel production from edible and non-edible vegetable oils. Fuel 2009, 88:1302-1306.
  • [51]Patil PD, Deng S, Rhodes I, Lammers P: Biodiesel production from waste cooking oil using ferric sulfate and supercritical methanol method. Fuel 2010, 89:360-364.
  • [52]King JW, Holliday RL, List GR: Hydrolysis of soybean oil in a subcritical water flow reactor. Green Chem 1999, 1:261-264.
  • [53]Demirbas A: Biodiesel from vegetable oils via transesterification in supercritical methanol. Energy Conversion Management 2002, 43:2349-2356.
  • [54]Demirbas A: Biodiesel fuels from vegetable oils via catalytic and noncatalytic supercritical alcohol transesterifications and other methods: a survey. Energy Conversion Management 2003, 44:2093-2109.
  • [55]Demirbas A: Biodiesel production from vegetable oils via catalytic and noncatalytic supercritical methanol transesterification methods. Progress in Energy and Combustion Science 2005, 31:466-487.
  • [56]Kusdiana D, Saka S: Kinetics of transesterification in rapeseed oil to biodiesel fuel as treated in supercritical methanol. Fuel 2001, 80:693-698.
  • [57]Kusdiana D, Saka S: Effects of water on biodiesel fuel production by supercritical methanol treatment. Bioresour Technol 2004, 91:289-295.
  • [58]Hernandez-Martin E, Otero C: Different enzyme requirements for the synthesis of biodiesel: Novozym1 435 and Lipozyme1 TL IM. Bioresour Technol 2008, 99(2):277-286.
  • [59]Hsu AF, Jones KC, Foglia TA, Marmer WN: Continuous production of ethyl esters of grease using an immobilized lipase. J Am Oil Chem Soc 2004, 81(8):749-752.
  • [60]Deng L, Xu XB, Haraldsson GG, Tan TW, Wang F: Enzymatic production of alkyl esters through alcoholysis: A critical evaluation of lipases and alcohols. J Am Oil Chem Soc 2005, 82(5):341-347.
  • [61]Dossat V, Combes D, Marty A: Continuous enzymatic transesterification of high oleic sunflower oil in a packed bed reactor: Influence of the glycerol production. Enzyme Microb Tech 1999, 25(3–5):194-200.
  • [62]Kumari V, Shah S, Gupta MN: Preparation of biodiesel by lipasecatalyzed transesterification of high free fatty acid containing oil from Madhuca indica. Energy Fuels 2007, 21(1):368-372.
  • [63]Roy I, Gupta MN: Applications of microwaves in biological sciences. Curr Sci 2003, 85:1685-1693.
  • [64]Azcan N, Danisman A: Alkali catalyzed transesterification of cottonseed oil by microwave irradiation. Fuel 2007, 86:2639-2644.
  • [65]Mazzocchia C, Kaddouri A, Modica G, Nannicini R: Advances in Microwave and Radio Frequency Processing. In Fast synthesis of biodiesel from triglycerides in presence of microwaves. Edited by Willert-Porada M. the Netherlands: Springer Berlin Heidelberg; 2006:370-376. Part V
  • [66]Refaat AA, El Sheltawy ST, Sadek KU: Optimum reaction time, performance and exhaust emissions of biodiesel produced by microwave irradiation. Int J Environ Sci Technol 2008, 5:315-322.
  • [67]Melo-Junior CAR, Albuquerque CER, Fortuny M, Dariva C, Egues S, Santos AF, Ramos ALD: Use of microwaves irradiation in the non-catalytic esterification of C18 fatty acids. Energy & Fuels 2009, 23:580-585.
  • [68]Yin J, Xiao M, Song J: Biodiesel from soybean oil in supercritical methanol with co-solvent. Energy Conversion Manage 2008, 49:908-912.
  • [69]Chen W, Wang C, Ying W, Wang W, Wu Y, Zhang J: Continuous production of biodiesel via supercritical methanol transesterification in a tubular reactor. Part 1: Thermophysical and transitive properties of supercritical methanol. Energy Fuels 2009, 23(1):526-532.
  • [70]Gedye RN, Smith FE, Westaway KC: The rapid synthesis of organic compounds in microwave ovens. Canad J Chem 1988, 66(1):17-26.
  • [71]Gedye RN, Smith FE, Westaway KC: The rapid synthesis of organic compounds in microwave ovens –Part 2. Canad J Chem 1991, 69:706.
  • [72]Wiesbrock F, Hoogenboom R, Schubert US: Microwave-assisted polymer synthesis: state-of-the-Art and future perspectives. Macromol Rapid Commun 2004, 25:1739-1764.
  • [73]Sinnwell S, Ritter H: Recent advances in microwave-assisted polymer synthesis. Aust J Chem 2007, 60:729-743.
  • [74]Lidstrom P, Tierney JP, Wathey B, Westman J: Microwave assisted organic synthesis – a review. Tetrahedron 2001, 57:9225-9283.
  • [75]Perreux L, Loupy A: A tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanistic considerations. Tetrahedron 2001, 57:9199-9223.
  • [76]Binner JGP, Hassine NA, Cross TE: The possible role of the pre-exponential factor in explaining the increased reaction rates observed during the microwave synthesis of titanium carbide. J Materials Sci 1995, 30(21):5389-5393.
  • [77]Kappe CO: Microwave dielectric heating in synthetic organic chemistry. Chem Sov Rev 2008, 37:1127-1139.
  • [78]Jermolovicius LA, Schneiderman B, Senise JT: Alteration of esterification kinetics under microwave irradiation. In Advances in microwave and radio frequency processing. Edited by Willert-Porada M. The Netherlands: Springer-Verlag Berlin Heidelberg; 2006:377-385. Part V
  • [79]Sim TS, Goh A, Becker EW: Comparison of centrifugation, dissolved air flotation and drum filtration techniques for garvesting sewage-grown algae. Biomass 1988, 16(1):51-62.
  • [80]Patil PD, Deng S: Transesterification of camelina sativa oil using heterogeneous metal oxide catalysts. Energy & Fuels 2009, 23:4619-4624.
  • [81]Schenk PM, Thomas-Hall SR, Stephens E, Marx UC, Mussgnug JH, Posten C, Kruse O, Hankamer B: Second generation biofuels: high-efficiency microalgae for biodiesel production. Bioenergy Res. 2008, 1:20-43.
  • [82]Sheehan J, Dunahay T, Benemann J, Roessler A: A look back at the US department of Energy’s aquatic species program-biodiesel from algae. National Renweable Energy Laboratory; 1998.
  • [83]Pienkos PT, Darzins A: The promise and challenges of microalgal-derived biofuels. Biofuels, Bioprod Bioref 2009, 3:431-440.
  • [84]Gressel J: Transgenics are imperative for biofuel crops. Plant Sci 2008, 174:246-263.
  • [85]Revellame E, Hernandez R, French W, Holmes W, Alley E: Biodiesel from activated sludge through in situ Transesterification. J Chem Technol Biotechnol 2010, 85:614-620.
  • [86]Giese J: Advances in microwave food-processing. Food Technology 1992, 46(9):118-123.
  • [87]Pare JRJ, Belanger JMR, Stafford SS: Microwave-assisted process (map(tm)) - a new tool for the analytical laboratory. Trac-Trends in Analytical Chem 1994, 13(4):176-184.
  • [88]Letellier M, Budzinski H: Microwave assisted extraction of organic compounds. Analusis 1999, 27(3):259-271.
  • [89]Spigno G, de Faveri DM: Microwave-assisted extraction of tea phenols: a phenomenological study. J Food Eng 2009, 93(2):210-217.
  • [90]Pan XJ, Niu GG, Liu HZ: Microwave-assisted extraction of tea polyphenols and tea caffeine from green tea leaves. Chem Eng Process 2003, 42(2):129-133.
  • [91]Hong N, Yaylayan VA, Raghavan GSV, Pare JRJ, Belanger JMR: Microwave-assisted extraction of phenolic compounds from grape seed. Nat Prod Lett 2001, 15(3):197-204.
  • [92]Guo ZK, Jin QH, Fan GQ, Duan YP, Qin C, Wen MJ: Microwave-assisted extraction of effective constituents from a Chinese herbal medicine Radix puerariae. Analytica Chimica Acta 2001, 436(1):41-47.
  • [93]Kiss GAC, Forgacs E, Cserhati T, Mota T, Morais H, Ramos A: Optimization of the microwave-assisted extraction of pigments from paprika (Capsicum annuum L.) powders. J Chromatogr A 2000, 889:41-49.
  • [94]Zigoneanu IG, Wilhams L, Xu Z, Sabliov CM: Determination of antioxidant components in rice bran oil extracted by microwave-assisted method. Bioresour Technol 2008, 99(11):4910-4918.
  • [95]Rostagno MA, Palma M, Barroso CG: Microwave assisted extraction of soy isoflavones. Analytica Chimica Acta 2007, 588(2):274-282.
  • [96]Terigar BG, Balasubramanian S, Boldor D, Xu Z, Lima M, Sabliov CM: Continuous microwave-assisted isoflavone extraction system-design and performance evaluation. Bioresour Technol 2010, 101(7):2466-2471.
  • [97]Eskilsson CS, Bjorklund E: Analytical-scale microwave-assisted extraction. J Chromatogr A 2000, 902(1):227-250.
  • [98]Bhattacharya M, Basak T: On the analysis of microwave power and heating characteristics for food processing: Asymptotes and resonances. Food Res Int 2006, 39(10):1046-1057.
  • [99]Hemwimon S, Pavasant P, Shotipruk A: Microwave-assisted extraction of antioxidative anthraquinones from roots of Morinda citrifolia. Sep Purif Technol 2007, 54:44-50.
  • [100]Lucchesi ME, Chemat F, Smadja J: Solvent-free microwave extraction of essential oil from aromatic herbs: comparison with conventional hydrodistillation. J Chromatogr A 2004, 1043:323-327.
  • [101]Nelson SO: Measurement of microwave dielectric properties of particulate materials. J Food Eng 1994, 21(3):365-384.
  • [102]Nuchter M, Ondruschka B, Bonrath W, Gum A: Microwave assisted synthesis – a critical technology overview. Green Chem 2004, 6:128-141.
  • [103]Virot M, Tomao V, Colnagui G, Visinoni F, Chemat F: New microwave-integrated Soxhlet extraction. An advantageous tool for the extraction of lipids from food products. J Chromatography A 2007, 1174(1–2):138-144.
  • [104]Duvernay WH, Assad JM, Sabliov CM, Lima M, Xu Z: Microwave extraction of antioxidant components from rice bran. Pharm Eng 2005, 25(4):1-5.
  • [105]Lee J, Yoo C, Jun S, Ahn C, Oh H: Comparison of several methods for effective lipid extraction from microalgae. Bioresour Technol 2010, 101(Suppl 1):S75-S77.
  • [106]Kanitkar AV: Parameterization of microwave assisted Oil extraction and its transesterification to biodiesel. Lousiana State University, Biological and Agricultural Engineering Department; 2010. [Master’s Thesis]
  • [107]Cooney M, Young G, Nagle N: Extraction of Bio-oils from microalgae. Separation & Purification Rev 2009, 38:291-325.
  • [108]Virot M, Tomao V, Ginies C, Visinoni F, Chemat F: Microwave-integrated extraction of total fats and oils. J Chromatogr A 2008, 1196–1197:57-64.
  • [109]Demirbas A: Biodiesel from sunflower oil in supercritical methanol with calcium oxide. Energy Conversion and Management 2007, 48:937-941.
  • [110]Loupy A, Petit A, Ramdani M, Yvanaeff C: The synthesis of esters under microwave irradiation using dry-media conditions. Can J Chem 1993, 71:90-95.
  • [111]Yuan H, Yang BL, Zhu GL: Synthesis of biodiesel using microwave absorption catalysts. Energy & Fuels 2009, 23:548-552.
  • [112]Perreux L, Loupy A: A tentative rationalization of microwave effects in organic synthesis according to the reaction medium and mechanistic considerations. Tetrahedron 2001, 57:9199-9223.
  • [113]Boldor D, Kanitkar A, Terigar BG, Leonardi C, Lima M, Breintenbeck GA: Microwave assisted extraction of biodiesel feedstock from the seeds of the invasive Chinese tallow tree. Environ Sci Technol 2010, 44:4019-4025.
  • [114]Tierney JP, Lidstrom P: Microwave assisted organic synthesis. Oxford, UK: CRC Press; 2005.
  • [115]Yuan H, Yang BL, Zhu GL: Synthesis of biodiesel using microwave absorption catalysts. Energy & Fuels 2009, 23:548-552.
  • [116]van Kasteren JMN, Nisworo AP: A process model to estimate the cost of industrial scale biodiesel production from waste cooking oil by supercritical transesterification. Resources Conservation and recycling 2007, 50:442-458.
  • [117]Demirbas A: Biodiesel from vegetable oils via transesterification in supercritical methanol. J Sci Ind Res 2005, 64:854-865.
  • [118]Patil PD, Gude VG, Lucy MC, Deng S: Microwave-assisted catalytic transesterification of camelina sativa Oil. Energy & Fuels 2010, 24(2):1298-1304.
  • [119]Patil PD, Gude VG, Deng S: Transesterification of camelina sativa oil using subcritical and supercritical methanol with Co-solvents. Energy & Fuels 2010, 24(2):746-751.
  • [120]Refaat A, Attia NK, Sibak HA, El Sheltawy ST, ElDiwani GI: Production optimization and quality assessment of biodiesel from waste vegetable oil. Int J Environ Sci Tech 2008, 5(1):75-82.
  • [121]Saifuddin N, Chua KH: Production of ethyl ester (biodiesel) from used frying Oil: optimization of transesterification process using microwave irradiation. Malays J Chem 2004, 6(1):77-82.
  • [122]Lertsathapornsuk V, Pairintra R, Krisnangkura K, Chindaruksa S: Direct conversion of used vegetable oil to biodiesel and its use as an alternative fuel for compression ignition engine. Proc First Int Conf Sustainable Energy and Green Architecture 2003, 2003:SE091-SE096.
  • [123]Lertsathapornsuk V, Ruangying P, Pairintra R, Krisnangkura K: Continuous transethylation of vegetable oils by microwave irradiation. Thailand; 2005:RE11-RE14. [Proceedings of the first international conference on energy network: 2005]
  • [124]Leadbeater NE, Barnard TM, Stencel LM: Batch and continuous-flow preparation of biodiesel derived from butanol and facilitated by microwave heating. Energy & Fuels 2008, 22:2005-2008.
  • [125]Mazzocchia C, Modica G, Martini F, Nannicini R, Venegoni D: Biodiesel and FAME from triglycerides over acid and basic catalysts assisted by microwave vol 7. Ancona, Italy: CR Chimie; 2004:601. [Proceedings of second international conference on microwave and its scientific applications: 2004]
  • [126]Zhang S, Zu Y-G, Fu Y-J, Luo M, Zhang D-Y, Efferth T: Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst. Bioresource Technology 2010, 101(3):931-936.
  • [127]Yaakob Z, Sukarman IS, Kamarudin SK, Abdullah SRS, Mohamed F: Production of biodiesel from jatropha curcas by microwave irradiation. Corfu, Greece; 2008:235-239. [Proceedings of the 2nd WSEAS/IASME International Conference on renewable energy sources: October 26-28 2008]
  • [128]Geuens J, Kremsner JM, Nebel BA, Schober S, Dommisse RA, Mittelbach M, Tavernier S, Kappe CO, Maes BUW: Microwave-assisted catalyst-free transesterification of triglycerides with 1-butanol under supercritical conditions. Energy Fuels 2008, 22:643-645.
  • [129]Moseley JD, Woodman EK: Energy efficiency of microwave- and conventionally heated reactors compared at meso scale for organic reactions. Energy Fuels 2009, 23:5438-5447.
  • [130]Barnard TM, Leadbeater NE, Boucher MB, Stencel LM, Wilhite BA: Continuous-flow preparation of biodiesel using microwave heating. Energy & Fuels 2007, 21:1777-1781.
  • [131]Bowman MD, Holcomb JL, Kormos CM, Leadbeater NE, Williams VA: Approaches for scale-Up of microwave-promoted reactions. Org Process Res Dev 2008, 12:41-57.
  • [132]Mazzocchia C, Modica G: Fatty acid methyl esters synthesis from triglycerides over heterogeneous catalysts in presence of microwaves. http://www.microwave-rf.org/MWRFApplKaddouri.pdf webcite
  • [133]Terigar BG: Advanced microwave technology for biodiesel feedstock processing. Louisiana State University, Biological and Agricultural Engineering Department; 2009. [Master’s Thesis]
  • [134]Terigar BG, Balasubramanian S, Boldor D: Effect of storage conditions on the Oil quality of Chinese tallow tree seeds. J Am Oil Chem Soc 2010, 87:573-582.
  • [135]Duz MZ, Saydut A, Öztürk G: Alkali catalyzed transesterification of safflower seed oil assisted by microwave irradiation. Fuel Process Technol 2011, 92:308-313.
  • [136]Hernando J, Leton P, Matia MP, Novella JL, Alvarez-Builla J: Biodiesel and FAME synthesis assisted by microwaves. Homogeneous batch and flow processes. Fuel 2007, 86(10–11):1641-1644.
  • [137]Majewski MW, Pollack SA, Curtis-Palmer VA: Diphenylammonium salt catalysts for microwave assisted triglyceride transesterification of corn and soybean oil for biodiesel production. Tetrahedron Letters 2009, 50:5175-5177.
  • [138]Rahmanlar I, Yucel S, Ozcimen D: The Production of methyl esters from waste frying oil by microwave method. Asia-Pacific Journal of Chemical Engineering 2012, 7(5):697-704.
  • [139]Nogueira BM, Carretoni C, Cruz R, Freitas S, Melo PA, Costa-Felix R, Pinto JC, Nele M: Microwave activation of enzymatic catalysts for biodiesel production. J Mol Catalysis B: Enzymatic 2010, 67:117-121.
  • [140]Lertsathapornsuk V, Pairintra R, Aryusuk K, Krisnangkura K: Microwave assisted in continuous biodiesel production from waste frying palm oil and its performance in a 100 kW diesel generator. Fuel Processing Technology 2008, 89(12):1330-1336.
  • [141]Azcan N, Danisman A: Microwave assisted transesterification of rapeseed oil. Fuel 2008, 87:1781-1788.
  • [142]Hsiao MC, Lin CC, Chang YH: Microwave irradiation-assisted transesterification of soybean oil to biodiesel catalyzed by nanopowder calcium oxide. Fuel 2011, 90(5):1963-1967.
  • [143]Kim D, Choi J, Kim G, Seol SK, Ha YC, Vijayan M, Jung S, Kim BH, Lee GD, Park SS: Microwave-accelerated energy-efficient esterification of free fatty acid with a heterogeneous catalyst. Bioresource Technology 2011, 102:3639-3641.
  • [144]Kamath HV, Regupathi I, Saidutta MB: Optimization of two step karanja biodiesel synthesis under microwave irradiation. Fuel Processing Technology 2011, 92:100-105.
  • [145]Shakinaz AES, Refaat AA, Shakinaz TES: Production of biodiesel using the microwave technique. J Adv Res 2010, 1(4):309-314.
  • [146]Suppalakpanya K, Ratanawilai SB, Tongurai C: Production of ethyl ester from esterified crude palm oil by microwave with dry washing by bleaching earth. Applied Energy 2010, 87:2356-2359.
  • [147]Zhang S, Zu YG, Fu YJ, Luo M, Zhang DY, Efferth T: Rapid microwaveassisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst. Bioresource Technology 2010, 101:931-936.
  • [148]Jin L, Zhang Y, Dombrowski JP, Chen C, Pravatas A, Xu L, Perkins C, Suib SL: ZnO/La2O2CO3 layered composite: a new heterogeneous catalyst for the efficient ultra-fast microwave biofuel production. Applied Catalysis B Environmental 2011, 103(1–2):200-205.
  • [149]Perin G, Alvaro G, Westphal E, Viana LH, Jacob RG, Lenardao EJ, D’Oca MGM: Transesterification of castor oil assisted by microwave irradiation. Fuel 2008, 87:2838-2841.
  • [150]Leadbeater NE, Stencel LM: Fast, easy preparation of biodiesel using microwave heating. Energy & Fuels 2006, 20(5):2281-2283.
  • [151]Duz MZ, Saydut A, Öztürk G: Alkali catalyzed transesterification of safflower seed oil assisted by microwave irradiation. Fuel Processing Technology 2011, 92:308-313.
  • [152]Hsiao MC, Lin CC, Chang YH, Chen LC: Ultrasonic mixing and closed microwave irradiation-assisted transesterification of soybean oil. Fuel 2010, 89(12):3618-3622.
  • [153]Ozturk G, Kafadar AB, Duz MZ, Saydut A, Hamamci C: Microwave assisted transesterification of maize (Zea mays L.) oil as a biodiesel fuel. Energy, Exploration & Exploitation 2010, 28(1):47-58.
  • [154]Han X, Chen L, Peng Q: Preparation of biodiesel from sunflower oil under microwave irradiation by ionic liquids H2SO4. Journal of Zhengzhou University (Engineering Science) 2008., 4
  • [155]Kong J, Han X, Chen L, Huo J: Preparation of biodiesel under microwave irradiation from sunflower Oil by solid super acid TiO2/SO4. Guangzhou Chemical Industry 2009., 2
  • [156]Chai F, Cao FH, Zhai FY, Chen Y, Wang XH, Su ZM: Transesterification of vegetable oil to biodiesel using a heteropolyacid solid catalyst. Adv Synth Catal 2007, 349:1057-1065.
  • [157]Shibasaki-Kitakawa N, Honda H, Kuribayashi H, Toda T, Fukumura T, Yonemoto T: Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst. Bioresource Technol 2007, 98:416-421.
  • [158]Brunschwig C, Moussavou W, Blin J: Use of bioethanol for biodiesel production. Progress in Energy and Combustion Science 2012, 38:283-301.
  • [159]Patil PD, Gude VG, Pinappu S, Deng S: Transesterification kinetics of Camelina sativa oil on metal oxide catalysts under conventional and microwave heating conditions. Chem Eng J 2011, 168(3):1296-1300.
  • [160]Zabeti M, Wan Daud D, Ashri M, Aroua MK: Activity of solid catalysts for biodiesel production: a review. Fuel Process Technol 2009, 90(6):770-777.
  • [161]Breccia A, Esposito B, Fratadocchi GB, Fini A: Reaction between methanol and commercial seed oils under microwave irradiation. J Microw Power Electromagn Energy 1999, 34(1):3-8.
  • [162]Schuchardt U, Serchelia R, Vargas RM: Transesterification of vegetable oils: a review. J. Braz. Chem. Soc. 1998, 9(1):199-210.
  • [163]Sridharan R, Mathai IM: Transesterification reactions. Sci Ind Res 1974, 22:178-187.
  • [164]Kulkarni MG, Dalai AK, Bakhshi NN: Transesterification of canola oil in mixed methanol/ethanol system and use of esters as lubricity additive. Bioresour Technol 2007, 98:2027-2033.
  • [165]Moser BR: Biodiesel production, properties, and feedstocks. In Vitro Cell Dev Biol—Plant 2009, 45:229-266.
  • [166]Chisti Y: Biodiesel from microalgae. Biotechnol Adv 2007, 25(3):294-306.
  • [167]Cooney MJ, Young G, Pate R: Bio-oil from photosynthetic microalgae: case study. Bioresour Technol 2011, 102(1):166-177.
  • [168]Lardon L, Helias A, Sialve B, Steyer J, Bernard O: Life-cycle assessment of biodiesel production from microalgae. Environmental science and technology 2009, 43:6475-6481.
  • [169]National Algal Biofuels Technology Roadmap: U.S. Department of energy, office of energy efficiency and renewable energy. USA: Biomass Program; 2010.
  • [170]Demirbas A: Production of biodiesel fuels from linseed oil using methanol and ethanol in non-catalytic SCF conditions. Biomass & Bioenergy 2009, 33:113-118.
  • [171]Ranjan A, Patil C, Moholkar VS: Mechanistic assessment of microalgal lipid extraction. Ind Eng Chem Res 2010, 49:2979-2985.
  • [172]Mandal V, Mohan Y, Hemalatha S: Microwave assisted extraction – an innovative and promising extraction tool for medicinal plant research. Pharmacognosy Reviews 2007, 1(1):7-18.
  • [173]Chen W, Sommerfeld M, Hu Q: Microwave assisted Nile red mentod for in vivo quantification of neutral lipids in microalge. Bioresource technology 2011, 101(1):135-141.
  • [174]Banapurmath NR, Tewari PG, Hosmath RS: Experimental investigations of a four-stroke single cylinder direct injection diesel engine operated on dual fuel mode with producer gas as inducted fuel and Honge oil and its methyl ester (HOME) as injected fuels. Renewable Energy 2007, 33:2007-2018.
  • [175]Bunyakiat K, Makmee S, Sawangkeaw R, Ngamprasertsith S: Continuous production of biodiesel via transesterification from vegetable oils in supercritical methanol. Energy Fuels 2006, 20:812-817.
  • [176]Demirbas A: Biodiesel production via non-catalytic SCF method and biodiesel fuel characteristics. Energy Convers Mgmt 2006, 47:2271-2282.
  • [177]Demirbas A: Studies on cottonseed oil biodiesel prepared in non-catalytic SCF conditions. Bioresource Technol 2008, 99:1125-1130.
  • [178]Demirbas A: Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification. Energy Convers Mgmt 2009, 50:923-927.
  • [179]Hawash S, Kamal N, Zaher F, Kenawi O, Diwani GE: Biodiesel fuel from Jatropha oil via non-catalytic supercritical methanol transesterification. Fuel 2009, 88:579-582.
  • [180]Madras G, Kolluru C, Kumar R: Synthesis of biodiesel in supercritical fluids. Fuel 2004, 83:2029-2033.
  • [181]Rathore V, Madras G: Synthesis of biodiesel from edible and non-edible oils in supercritical alcohols and enzymatic synthesis in supercritical carbon dioxide. Fuel 2007, 86:2650-2659.
  • [182]Song ES, Lim JW, Lee HS, Lee YW: Transesterification of RBD palm oil using supercritical methanol. J Supercrit Fluids 2008, 44:356-363.
  • [183]Varma MN, Madras G: Synthesis of biodiesel from castor oil and linseed oil in supercritical fluids. Ind Eng Chem Res 2007, 46:1-6.
  • [184]Vieitez I, Silva C, Alckmin I, Borges GR, Corazza FC, Oliveira JV, Grompone MA, Jachmanian I: Effect of temperature on the continuous synthesis of soybean esters under supercritical ethanol. Energy Fuels 2009, 23:558-563.
  • [185]Young G, Nippgen F, Titterbrandt S, Cooney MJ: Lipid extraction from biomass using co-solvent mixtures of ionic liquids and polar covalent molecules. Sep Purification Technol 2010, 72:118-121.
  • [186]Johnson MB, Wen Z: Production of biodiesel from the microalga Schizochytrium limacinum by direct transesterification of algal biomass. Energy Fuels 2009, 23:5179-5183.
  • [187]Aresta M, Dibenedetto A, Carone M, Colonna T, Fragale C: Production of biodiesel from macroalgae by supercritical CO2 extraction and thermochemical liquefaction. Environ Chem Lett 2005, 3:136-139.
  • [188]Patil PD, Gude VG, Mannarswamy A, Deng S, Cooke P, Munson-McGee S, Rhodes I, Lammers P, Khandan NN: Optimization of direct conversion of Wet algae to biodiesel under supercritical methanol conditions. Bioresour Technol 2011, 102(1):118-122.
  • [189]Patil PD, Gude VG, Mannarswamy A, Deng S, Cooke P, Munson-McGee S, Rhodes I, Lammers P, Khandan NN: Optimization of microwave-assisted transesterification of dry algal biomass using RSM. Bioresour Technol 2011, 102(2):1399-1405.
  • [190]Patil PD, Gude VG, Mannarswamy A, Cooke P, Khandan NN, Lammers P, Deng S: Comparison of direct transesterification of algal biomass under supercritical methanol and microwave irradiation conditions. Fuel 2012, 97:822-831.
  • [191]Koberg M, Cohen M, Ben-Amotz A, Gedanken A: Bio-diesel production directly from the microalgae biomass of Nannochloropsis by microwave and ultrasound radiation. Bioresour Technol 2011, 102(5):4265-4269.
  • [192]Encinar JM, Gonzalez JF, Martinez G, Sanchez N, Pardal A: Soybean oil transesterification by the use of a microwave flow system. Fuel 2012, 95:386-393.
  • [193]Kumar R, Kumar GR, Chandrashekar N: Microwave assisted alkali-catalyzed transesterification of Pongamia pinnata seed oil for biodiesel production. Bioresour Technol 2011, 102(11):6617-6620.
  • [194]Vijayaraghavan K, Hemanathan K: Biodiesel production from freshwater algae. Energy Fuels 2009, 23:5448-5453.
  • [195]Hill J, Nelson E, Tilman D, Polasky S, Tiffany D: Environmental, economic, and energetic costs and benefits of biodiesel and ethanol biofuels. PNAS 2006, 103(30):11206-11210.
  • [196]Scott SA, Davey MP, Dennis JS, Horst I, Howe CJ, Lea-Smith DJ, Smith AG: Biodiesel from algae: challenges and prospects. Current Opinion in Biotechnology 2010, 21:277-286.
  • [197]Energy life-cycle assessment of soybean biodiesel. USA; 2009. [USDA agricultural economic report number 845]
  • [198]Pimentel D, Patzek TW: Ethanol production using corn, Switchgrass, and wood; biodiesel production using soybean and sunflower. Nat Resour Res 2005, 14(1):65-76.
  • [199]Janulis P: Reduction of energy consumption in biodiesel fuel life cycle. Renewable Energy 2004, 29:861-871.
  • [200]Jorquera O, Kiperstok A, Sales Emerson A, Embiruc¸u M, Ghirardi Maria L: Comparative energy life-cycle analyses of microalgal biomass production in open ponds and photobioreactors. Renew Bioresour Technol 2010, 101:1406-1413.
  • [201]Singh J, Gu S: Commercialization potential of microalgae for biofuels production. Renewable and Sustainable. Energy Rev 2010, 14:2596-2610.
  • [202]Illman AM, Scragg AH, Shales SW: Increase in Chlorella strains calorific values when grown in low nitrogen medium. Enzyme Microb Technol 2000, 27:631-635.
  • [203]Xu L, Brilman DWF, Withag JAM, Brem G, Kersten S: Assessment of a dry and a wet route for the production of biofuels from microalgae: energy balance analysis. Bioresource Technol 2011, 102(8):5113-5122.
  • [204]Brune DE, Lundquist TJ, Benemann JR: Microalgae biomass for greenhouse gas reductions: potential for replacement of fossil fuels and animal feeds. J Environ Eng 2009, 135(11):1136-1144.
  • [205]Patil PD, Gude VG, Reddy HK, Muppaneni T, Deng S: Biodiesel production from waste cooking Oil using sulfuric acid and microwave irradiation processes. J Environm Prot 2012, 3:107-113.
  • [206]Chand P, Chintareddy VR, Verkade JG, Grewell D: Enhancing biodiesel production from soybean Oil using ultrasonics. Energy Fuels 2010, 24(3):2010-2015.
  • [207]Hill JM, Marchant TR: Modelling microwave heating. App Math Model 1996, 20(1):3-15.
  • [208]Reimbert CG, Minzoni AA, Smyth NF: Effect of radiation losses on hotspot formation and propagation in microwave heating. IMA J Applied Math 1996, 57(2):165-179.
  • [209]Kappe CO, Stadler A: Microwaves in organic and medicinal chemistry. KGaA, Weinheim: Wiley-VCH Verlag GmbH & Co; 2005.
  • [210]Kappe CO, Dallinger D, Murphree SS: Practical microwave synthesis for organic chemists: strategies, instruments, and protocols. Wiley, John & Sons; 2009.
  • [211]Leadbeater NE: Microwave heating as a tool for sustainable chemistry. CRC Press; 2010.
  • [212]Boldor D, Balasubramanian S, Purohit S, Rusch KA: Design and implementation of a continuous microwave heating system for ballast water treatment. Environ Sci Technol 2008, 42(11):4121-4127.
  • [213]Glasnov TN, Kappe CO: Microwave-assisted synthesis under continuous-flow conditions. Macromol Rapid Commun 2007, 28:395-410.
  • [214]Baxendale IR, Hayward JJ, Ley SV: Microwave reactions under continuous flow conditions. Comb Chem High Throughput Screen 2007, 10(10):802-836.
  • [215]Salvi D, Boldor D, Ortego J, Aita GM, Sabliov CM: Numerical modeling of continuous flow microwave heating: a critical comparison of COMSOL and ANSYS. J Microw Power Electromagn Energy 2010, 44(4):187-197.
  • [216]Moseley JD, Lenden P, Lockwood M, Ruda K, Sherlock J, Thomson AD, Gilday JP: A comparison of commercial microwave reactors for scale-Up within process chemistry. Org Process Res Dev 2008, 12:30-40.
  • [217]Cleophax J, Liagre M, Loupy A, Petit A: Application of focused microwaves to the scale-Up of solvent-free organic reactions. Org Proc Res Dev 2000, 4(6):498-504.
  • [218]Letellier M, Budzinski H, Garrigues P, Wise S: Focused microwave-assisted extraction of polycyclic aromatic hydrocarbons in open cell from reference materials (sediment, soil, air particulates). Spectroscopy 13:71-80. 1996/1997
  • [219]Leonelli C, Mason TJ: Microwave and ultrasonic processing: now a realistic option for industry. Chem Eng Process 2010, 49:885-900.
  • [220]Bohlmann JT, Lorth CM, Drews A, Buchholz R: Microwave high pressure thermo-chemical conversion of sewage sludge as an alternative to incineration. Chem Engr Technol 1999, 21:404-409.
  • [221]Domínguez A, Menéndez JA, Inguanzo M, Pis JJ: Gas chromatographic–mass spectrometric study of the oils fractions produced by microwave-assisted pyrolysis of different sewage sludges. J Chromatogr A 2003, 1012:193-206.
  • [222]Dominguez A, Menendez JA, Inguanzo M, Pis JJ: Investigations into the characteristics of oils produced from microwave pyrolysis of sewage sludge. Fuel Process Technol 2005, 86:1007-1020.
  • [223]Tian Y, Zuo W, Ren Z, Chen D: Estimation of a novel method to produce bio-oil from sewage sludge by microwave pyrolysis with the consideration of efficiency and safety. Bioresource Technol 2011, 102:2053-2061.
  • [224]Zuo W, Tian Y, Ren N: The important role of microwave receptors in bio-fuel production by microwave-induced pyrolysis of sewage sludge. Waste Manage 2011, 31:1321-1326.
  • [225]Ozcimen D, Yucel S: Novel methods in biodiesel production. Edited by DosSantos MA. Intech; 2011:354-384. [Biofuel’s Engineering process technology]
  • [226]Microwave·Uv·Us synthesis/extraction reactor UWave-1000 http://www.sineo.cn/en/Products_px.asp?pid=47 webcite
  • [227]Li H, Pordesimo LO, Weiss J, Wilhelm LR: Microwave and ultrasound assisted extraction of soybean oil. Trans ASAE 2004, 47:1187-1194.
  • [228]Cravotto G, Boffa L, Mantegna S, Perego P, Avogadro M, Cintas P: Improved extraction of vegetable oils under high-intensity ultrasound and/or microwaves. Ultrason Sonochem 2008, 15(5):898-902.
  • [229]Lagha A, Chemat S, Bartels PV, Chemat F: Microwave - ultrasound combined reactor suitable for atmospheric sample preparation procedure of biological and chemical products. Analusis 1999, 27:452-457.
  • [230]Cravotto G, Cintas P: The combined use of microwaves and ultrasound: improved tools in process chemistry and organic synthesis. Chemistry 2007, 3(7):1902-1909.
  • [231]Liu S, Wang Y, McDonald T, Taylor SE: Efficient production of biodiesel using radio frequency heating. Energy & Fuels 2008, 22:2116-2120.
  • [232]Toukoniitty B, Mikkola J, Murzin DY, Salmi T: Utilization of electromagnetic and acoustic irradiation in enhancing heterogeneous catalytic reactions. Applied Catalysis A: General 2005, 279:1-22.
  • [233]Metaxas AC: Foundations of electroheat: a unified approach. John & Sons: Wiley; 1996.
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