A promising fuel cell catalyst using non-precious metal oxide

4th International Conference on Advanced Sciences

工业技术;自然科学

Mohamed, Hamdy F.M.^1,2 ; Abdel-Hady, E.E.^1 ; Hmamm, M.F.M.^2 ; Ibrahim, M.^1 ; Ahmed, H.^1 ; Mondy, M.^1 ; Yehia, H.^1

Physics Department, Faculty of Science, Minia University, P.O. Box, Minia

61519, Egypt^1

Renewable Energy Science and Engineering Department, Faculty of Postgraduate Studies for Advanced Science (PSAS), Beni-Suef University, P.O. Box, Beni-Suef

62511, Egypt^2

关键词: Calcination temperature;    Characteristic vibration band;    Fourier transformations;    Fuel cell application;    Non-precious catalysts;    Oxidation behaviours;    Poly (vinyl alcohol) (PVA);    Zinc oxide nanoparticles;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/464/1/012002/pdf
DOI  :  10.1088/1757-899X/464/1/012002

来源: IOP

【 摘 要 】

Fuel cell has two essential problems, its cost and the durability, which hinder its commercialization. Platinum is the ideal catalyst that has high activity, stability and selectivity but has high cost. An attempt has been done to find a cheaper catalyst instead of platinum. Zinc oxide nanoparticles were synthesized via sol-gel method using zinc acetate and citric acid in basic media with different calcination temperatures (420, 520 and 620 °C). From X-ray diffraction (XRD) patterns, the calculated particles size is 7.7, 15.6 and 19.3 nm as the calcination temperature of 420, 520 and 620°C, respectively, indicating that the particles size increases with increasing the calcination temperature. Different concentrations (5 and 10 wt.%) of ZnO nanoparticles with 10 wt.% polyvinyl alcohol (PVA) were prepared and calcinated at 750 °C to get carbon/ZnO as a catalyst for fuel cell applications. A carbon core-shell surrounding by mono-disperse ZnO nanoparticles with large surface area that required for the new catalyst with believable morphology was shown by transmission electron microscope (TEM). Also, XRD presents high purity of the new composite with uniformly distinguishable peaks. Fourier transformation infrared (FTIR) spectroscopy shows the change in the carbon/ZnO nanoparticles spectra due to ZnO characteristic vibration band at 440-460 cm-1. Cyclic voltammetry (CV) exhibits a good promising catalytic activity and current density with oxidation behaviour is reported. Finally, ZnO used to enhance carbon electrochemically performance as a result of a novel non-precious catalyst.