International Fundamentum Science Symposium 2018 | |
Synthesis and crystal structure of dinuclear based coordination polymer derived from N-6-[(4-pyridylmethylamino)carbonyl]-2-pyridinecarboxylic acid methyl ester | |
自然科学;工业技术 | |
Kadir, M.A.^1,2 ; Mansor, S.M.T.^2 ; Mehamod, F.S.^1,2 ; Yusof, M.S.M.^2 | |
Advanced Nano Materials Research Group (ANoMa), School of Fundamental Science, Universiti Malaysia Terengganu, Kuala Nerus, Terengganu | |
21030, Malaysia^1 | |
School of Fundamental Science, Universiti Malaysia Terengganu, Kuala Nerus, Terengganu | |
21030, Malaysia^2 | |
关键词: Coordination Polymers; Copper perchlorates; Intra-molecular hydrogen bonds; Monoclinic crystal systems; One-dimensional coordination polymer; One-dimensional networks; Perchlorate anions; Synthesis and crystal structure; | |
Others : https://iopscience.iop.org/article/10.1088/1757-899X/440/1/012022/pdf DOI : 10.1088/1757-899X/440/1/012022 |
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来源: IOP | |
【 摘 要 】
This study describes the facile synthesis and crystal structure of one dimensional coordination polymer which has been successfully obtained from reaction between semi rigid monoamide ligand namel N6-[(4-pyridylmethylamino)carbonyl]-2-pyridinecarboxylic acid methyl ester (L2) with copper perchlorate. The synthesized coordination polymer, with formula given by elemental analysis and X-ray crystallography as {[Cu3(L2-CH3)3(L2)2(H2O)2(CH3OH)](ClO4)3}n was crystallized in monoclinic crystal system and space group C2/c. The asymmetric unit of this complex consists of three copper atoms, three anionic carboxylate forms of ligand L2, two neutral forms of ligand L2 and four partially-occupied non-coordinated perchlorate anions. This asymmetric unit acts as the repeating fragment to form one-dimensional networks which was stabilized by intramolecular hydrogen bonds.
【 预 览 】
Files | Size | Format | View |
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Synthesis and crystal structure of dinuclear based coordination polymer derived from N-6-[(4-pyridylmethylamino)carbonyl]-2-pyridinecarboxylic acid methyl ester | 290KB | download |