Dynamic adsorption of mixtures of Rhodamine B, Pb (II), Cu (II) and Zn(II) ions on composites chitosan-silica-polyethylene glycol membrane

12th Joint Conference on Chemistry

Mahatmanti, F.W.^1 ; Rengga, W.D.P.^2 ; Kusumastuti, E.^1 ; Nuryono^3

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Semarang, 50229, Indonesia^1

Department of Chemical Engineering, Faculty of Engineering, Universitas Negeri Semarang, 50229, Indonesia^2

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta

55281, Indonesia^3

关键词: Adsorption membranes;    Adsorptive membranes;    Chitosan membrane;    Dynamic adsorption;    Flexible membranes;    Hydrophilic properties;    Rhodamine B dye;    Solution mixtures;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/349/1/012022/pdf
DOI  :  10.1088/1757-899X/349/1/012022

来源: IOP

【 摘 要 】

The adsorption of a solution mixture of Rhodamine B, Pb (II), Cu (II) and Zn(II) was studied using dynamic methods employing chitosan-silica-polyethylene glycol (Ch/Si/P) composite membrane as an adsorptive membrane. The composite Ch/Si/P membrane was prepared by mixing a chitosan-based membrane with silica isolated from rice husk ash (ASP) and polyethylene glycol (PEG) as a plasticizer. The resultant composite membrane was a stronger and more flexible membrane than the original chitosan-based membrane as indicated by the maximum percentage of elongation (20.5 %) and minimum Young's Modulus (80.5 MPa). The composite membrane also showed increased mechanical and hydrophilic properties compared to the chitosan membranes. The membrane was used as adsorption membrane for Pb (II), Cu (II), Cd (II) ions and Rhodamine B dyes in a dynamic system where the permeation and selectivity were determined. The permeation of the components was observed to be in the following order: Rhodamine B > Cd (II) > Pb (II) > Cu (II) whereas the selectivity was shown to decrease the order of Cu (II) > Pb (II) > Cd (II) > Rhodamine B.