Kinetic and mechanism formation reaction of complex compound Cu with di-n-buthildithiocarbamate (dbdtc) ligand

12th Joint Conference on Chemistry

Haryani, S.^1 ; Kurniawan, C.^1 ; Kasmui^1

Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Negeri Semarang, Indonesia^1

关键词: Chemical computation;    Complex compounds;    Formation reaction;    Metal dithiocarbamate;    Optimum reaction conditions;    Reaction mechanism;    Reaction synthesis;    Wide-ranging applications;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/349/1/012060/pdf
DOI  :  10.1088/1757-899X/349/1/012060

来源: IOP

【 摘 要 】

Synthesis of complex compound is one field of research which intensively studied. Metal-dithiocarbamate complexes find wide-ranging applications in nanomaterial and metal separation science, and have potential use as chemotherapeutic, pesticides, and as additives to lubricants. However, the information about is reaction kinetic and mechanism are very much lacking. The research and analyzes results show that reaction synthesis ligand DBDTC and complex compounds Cu-DBDTC. Optimum reaction condition of formation of complex compounds Cu with DBDTC at pH=3, [DBDTC] = 4.10-3M, and the time of reaction 5 minutes. Based the analysis varian reaction of complex compounds at pH 3 and 4, diffrence significance at the other pH: 5; 5,5; 6; 6,5 ; 7; and 8. The various of mole with reactants comosition difference sigbificance, those the time reaction for 5 and 6 minutes diffrence by significance with the other time, it is 3,4,8, and 10 minutes. The great product to at condition pH 6, the time optimum at 5 minutes and molar ratio of logam: ligand = 1:2. The reaction kinetic equation of complex compound Cu with chelathing ligand DBDTC is V=0.917106 [Cu2+]0.87921[DBDTC]2.03021. Based on the kinetic data, and formed complex compounds estimation, the mechanism explaining by 2 stages. In the first stage formation of [Cu(DBDTC)], and then [Cu(DBDTC)2] with the last structure geomethry planar rectangle. The result of this research will be more useful if an effort is being done in reaction mechanism by chemical computation method for obtain intermediate, and for constant "k" in same stage, k1.k2. and compound complex constanta (β).