Study of Catalyst Variation Effect in Glycerol Conversion Process to Hydrogen Gas by Steam Reforming

12th Joint Conference on Chemistry

Widayat^1,2 ; Hartono, R.^1 ; Elizabeth, E.^1 ; Annisa, A.N.^1

Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jalan Prof Soedarto, SH, Tembalang, Semarang, Central Java

50725, Indonesia^1

Laboratory of Material Technology, Central of Research and Service Diponegoro University, Jalan Prof Soedarto, SH, Tembalang, Semarang, Central Java

50725, Indonesia^2

关键词: Alternative energy;    Biodiesel production;    Catalyst impregnations;    Catalyst preparation;    Economic development;    Glycerol conversions;    Process production;    Thermo chemical process;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/349/1/012070/pdf
DOI  :  10.1088/1757-899X/349/1/012070

来源: IOP

【 摘 要 】

Along with the economic development, needs of energy being increase too. Hydrogen as alternative energy has many usages. Besides that, hydrogen is one source of energy that is a clean fuel, but process production of hydrogen from natural gas as a raw material has been used for a long time. Therefore, there is need new invention to produce hydrogen from the others raw material. Glycerol, a byproduct of biodiesel production, is a compound which can be used as a raw material for hydrogen production. By using glycerol as a raw material of hydrogen production, we can get added value of glycerol as well as an energy source solution. The process production of hydrogen by steam reforming is a thermochemical process with efficiency 70%. This process needs contribution of catalyst to improve its efficiency and selectivity of the process. In this study will be examined the effect variation of catalyst for glycerol conversion process to hydrogen by steam reforming. The method for catalyst preparation was variation of catalyst impregnation composition, catalyst calcined with difference concentration of hydrochloric acid and calcined with difference hydrochloric acid ratio. After that, all of catalyst which have been prepared, used for steam reforming process for hydrogen production from glycerol as a raw material. From the study, the highest yield of hydrogen gas showed in the process production by natural zeolite catalyst with 1:15 Hydrochloric acid ratio was 42.28%. Hydrogen yield for 2M calcined natural zeolite catalyst was 38.37%, for ZSM-5 catalyst was 15.83%, for 0.5M calcined natural zeolite was 13.09% and for ultrasonic natural zeolite was 11.43%. The lowest yield of hydrogen gas showed in catalyst 2Zn/ZSM-5 with 11.22%. This result showed that hydrogen yield product was affected by catalyst variation because of the catalyst has difference characteristic and difference catalytic activity after the catalyst preparation process.