Preparation and characterization compatible pellets for immobilization of colloidal sulphur nanoparticles

3rd International Conference on Chemical Engineering Sciences and Applications 2017

Adlim, M.^1 ; Zarlaida, F.^1 ; Khaldun, I.^1 ; Dewi, R.^1 ; Jamilah, M.^1

Chemistry Department, FKIP Syiah Kuala University, Darussalam, Banda Aceh

23111, Indonesia^1

关键词: Binding agent;    Disperse particles;    Immobilization method;    Mercury pollution;    Mercury vapour;    Pellet surfaces;    Rice husk ash;    Sulphur content;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/334/1/012041/pdf
DOI  :  10.1088/1757-899X/334/1/012041

来源: IOP

【 摘 要 】

Mercury pollution in atmosphere is dominated by mercury vapour release from coal burning and gold-amalgam separation in gold mining. The initial steps in formulating a compatible mercury absorbent for mercury stabilization was fabrication of pellet supported colloidal sulphur. Sulphur is used to stabilize mercury vapour by formation of metacinnabar that has much lower toxicity. The sulphur reactivity toward mercury vapour can be enhanced by using colloidal sulphur nanoparticles immobilized on compatible pellets. Clay pellets would have heat resistance but in fact, they were less stable in aqueous solution although their stability increased with inclusion of rice husk ash and sawdust or pineapple leaf fibre in the composite. Pellets made of rice husk ash and polyvinyl acetate were stable in water at least for 24 hours. Sulphur from thiosulfate precursor that immobilized onto surface of pellet using chitosan as the stabilizer and the binding agent gave lower sulphur content compared to sulphur from other precursors (sulphur powder and sulphur-CS2). Sulphur from thiosulfate precursor was in form of colloid, has nanosize, and disperse particles on the surface of rice husk ash pellets. Sulphur immobilization methods affect on sulphur particles exposure on the pellet surface.