Preparation and characterization of Schiff base Cu(II) complex and its applications on textile materials

17th World Textile Conference AUTEX 2017 - Shaping the Future of Textiles

Oylumluoglu, G.^1 ; Oner, J.^2

Mugla Sitki Koçman University, Department of Physics, Molecular Nano-Materials Laboratory, Mugla, Turkey^1

Usak University, Civil Engineering Department, Usak, Turkey^2

关键词: Bleaching treatment;    Blue emission bands;    Copper complexes;    Green emission bands;    Luminescent property;    Schiff-base ligands;    Single crystal x-ray diffraction;    Textile applications;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/254/10/102009/pdf
DOI  :  10.1088/1757-899X/254/10/102009

来源: IOP

【 摘 要 】

Schiff base ligands are regarded as an important class of organic compounds on account of the fact that their complexation ability with transition metal ions. A new monomeric Schiff base Cu(II) complex, [Cu(HL)2], 1 [H2L = 2-((E)-(2-hydroxypropylimino)methyl)-4-nitrophenol] has been synthesized and characterized by elemental analysis, UV and IR spectroscopy, single crystal X-ray diffraction and photoluminescence study. While the Schiff base ligand and its Cu(II) complex are excited at λex= 349 nm in UV region, the Schiff base ligand shows a blue emission band at λmax= 480 nm whereas its Cu(II) complex shows a strong green emission band at λmax= 520 nm in the solid state at room temperature. The luminescent properties showed that the Schiff base ligand and its Cu(II) complex can be used as novel potential candidates for applications in textile such as UV-protection, antimicrobial, laundry and functional bleaching treatments.