Durability of a fin-tube latent heat storage using high density polyethylene as PCM

3rd International Conference on Innovative Materials, Structures and Technologies

Zauner, Christoph^1 ; Hengstberger, Florian^1 ; Etzel, Mark^1 ; Lager, Daniel^1 ; Hofmann, Rene^1 ; Walter, Heimo^2

AIT Austrian Institute of Technology GmbH, Center for Energy, Sustainable Thermal Energy Systems, Giefinggasse 2, Wien

1210, Austria^1

Vienna University of Technology, Institute for Energy Systems and Thermodynamics, Getreidemarkt 9BA, Wien

1060, Austria^2

关键词: Fin-tube heat exchangers;    Heating and cooling cycles;    High density polyethylene(HDPE);    Melting and crystallization;    Power characteristic;    Recycled materials;    Temperature profiles;    Thermophysical characterization;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/251/1/012123/pdf
DOI  :  10.1088/1757-899X/251/1/012123

来源: IOP

【 摘 要 】

Polymers have rarely been used as storage materials in latent heat storages up to now. Thus, we systematically screened all polymers available on a large-scale, selected promising ones based on their theoretical properties and experimentally tested more than 50 candidates. We found that polyethylene, polyoxymethylene and polyamides are promising even as recycled material. Especially high density polyethylene (HDPE) turned out to be suitable as was shown by detailed thermophysical characterization including more than 1000 heating and cooling cycles for INEOS Rigidex HD6070EA. We built a storage with 170 kg HDPE and a total mass of 600 kg based on a fin-Tube heat exchanger and characterized its energy capacity, power characteristics and temperature profiles using a thermal oil test rig. In total we performed 30 melting and crystallization cycles where the whole storage was above 100 °C for more than 140 hours. After usage we examined the interior of the storage by cutting it into various pieces. A thin layer of degradation was observed on the surfaces of the PCM which is most likely related to thermo-oxidative degeneration of HDPE. However, the bulk of the PCM is still intact as well as the heat exchanger itself.