Preparation of Biopolyol by Solvolysis Liquefaction of Oil Palm Mesocarp Fibre using Polyhydric Alchohol

International Research and Innovation Summit 2017

Kormin, Shaharuddin^1 ; Rus, Anika Zafiah M.^1 ; Azahari, M Shafiq M^1

Sustainable Polymer Engineering, Advanced Manufacturing and Material Center (SPEN-AMMC), Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein Onn Malaysia, Johor, Parit Raja, Johor, Batu Pahat

86400, Malaysia^1

关键词: Conversion technology;    Fourier transform infra red (FTIR) spectroscopy;    High reaction temperatures;    Hydroxyl values;    Natural materials;    Polyurethane Foam;    Polyurethane foams;    Polyurethane synthesis;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/226/1/012046/pdf
DOI  :  10.1088/1757-899X/226/1/012046

来源: IOP

【 摘 要 】

Liquefied oil palm mesocarp fibre (LOPMF) is a promising natural material that can be used as biopolyol of polyurethane foam. The aim of this study was to utilizing solvolysis liquefaction conversion technology of oil palm mesocarp fibre (OPMF) for polyurethane (PU) foam. LOPMF was obtained with liquefaction of fibre in polyhydric alchohol (PA) such as ethylene glycol (EG), polyethylene glycol (PEG) and glycerol (GLY) as liquefaction solvent and sulphuric acid (H2SO4) in three different OPMF/PA ratio (1/2, 1/3 and 1/4) in conventional glass reactor. During the liquefaction, cellulose, semi-cellulose and lignin are decomposed, which results in changes of acid value and hydroxyl value. Liquefied OPMF and residues were characterized by Fourier transform infrared (FT-IR) spectroscopy. The results revealed that almost 50% of the OPMF converted into biopolyol product within 2 hours with OPMF/PA ratio of 1/4. Biopolyol produced under different condition showed viscosities from 210 to 450 Pa.s. The hydroxyl and acid values of the liquefied OPMF varied with the liquefied conditions. It was observed that with an increase in the liquefaction solvent (PA) amount in the mixture resulted in a high acid value and hydroxyl value for the OPMF. High reaction temperature combining with low OPMF material to solvent ratio resulted low hydroxyl number of LOPMF. The result in this study showed that biopolyol was suitable monomer for polyurethane synthesis.